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ln_1997_199 MT

Regulations, 1997

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Malta Government Gazette — Legal Notice 1997 199 — Regulations, 1997

.'000, DRUGS AND DRINKING WATER ACT

(CAP. 231)

Colours (Use in Foodstuffs) (Amendment)

Regulations, 1997

IN exercise of the powers conferred by section 12 of the food .

Drugs and Drinking Water Act. the Mini ster of Health, Care of the

Elde rl y and Fami ly Affairs. 011 the adv ice of the Malta

Standardisation Authority . has made the following regu lations;-

I. ( I) These regulations may be cited as the Colours (Use

in Foodstuffs) (Amendment) Regulations, 1997 and shall be read

and construed as one with the Colours (Use in Foodstuffs)

Re gulation s, 1995, he reinafter referred to as "the princi pal LJi . 1070( IW~ .

(2) These regulations shall come into force on the 1st

Malta Government Gazette — Legal Notice 1997 199 — Regulations, 1997

For the Sixth Schedule to the principal regulations the re SuboIiI.-"""

SiJ.1I! ScI!cduk

shall be substituted the follow ing:-

"' .... prioocipol

rrpUD<>M.

"S IXTH SCHEDULE

Pari I - General speciOcallons for aluminium lakes of colours

Alum inium tun.,., p..,parrd by n.'xting ooIouB complying willi !he purity

criteria set OUt in the approprialc specirlCaUon monograptl wilh alumiNi under

.:j\l(()\ll oonditi<)n • . The alum;NI i$ usually freshly pre~ undried material

made by reacting aluminium !Ou lrate or c hloride with sodium or calcium

carbon~te or bicarbonate or ammonia. Foliowing lake fonnation, !he ~OCt

is filtered. washed with waler and dried. Unreacted alumina may also ~

Pn.'sent in the fini shed prodllCl.

Not mon: IiwI O,N (under ""utnl conditions)

Spedfic purity criteri~ for the rom:spooding colours are applicable .

Part II - Specific Criteria or Purity

CI NalUral YellOW 3, Tp~rk Ye llow. Diferoyl Methane

Curcumin ;s obuoinnt by soIvenl el lraction of turmeric Le . the ground

rh i~om n of na1Ural slrains of C~rr~ ma I(mga L. [n order 10 oblain a

oon«rMraltd CUKumin powder , 1'-' CAlIlICt is puri FIed by CT)ouJlization.

Tilt prodUCt consists essentially o f curc umins ; i .c. \he colouring principle

(',7-bis( 4-hydro~ y-J..me!bo~ypheny')hqna- [ M~n-) ,S-dione) and in two

desmethoxyderi"alives in vlI)'in, proportioru. Minor amounts of oi ls and

",sins naturally ocrurios in turmeric may be p",scm.

Only the folio wio, .olvents may be u$Cd in !he un-action: ethylIKCUlte.

an'~. carbon dioxi de. dichlorometh ..... . n-butanol , methanol . elhanol,

be:t ane.

moo

207-280-j

I ,7. Bi.(4- hydro~y-3-metbolyphenyl}hepla_1 , 6-dic .... ·3.5-diooe

II 1-( 4-Hydroxyphenyl)-1-( 4-hydroxy-)· methox y-phenyl-)hepta-I ,6-

dienc:-3.5-diooe

[ .7-Bis( 4-hydroxyphcnyl)hepla-I.6-die .... ·) .5-dione

!II

C"I~~O.

J1l C,.H .. O.

I. 368.39

II. 33&.39

!II. 3Og,l9

E :~m I 607 atca 426nminethaool

Max imum in ethanol at CI <126 nm

179-182"C

Ethylacetate

A~_

n-butanol.

M,""""

Not ~ than SO m&fkg .singly or in combination

"""'"

Huane

nOt more than 10 m&fkg

Didllol'Ofll(:lhane

Not more lllan 3 m&lkg

Not more than 10 mglks

Not more than 1 mglkg

Not more than 1 mglkg

Not more than 40 mgll.,

Lactoflavin

I$OI.Uoxuine

201-S07-1

7 $- Dimethyl. I a.(D-ribo-2,3 ,4 j-letnhydJ"ox ypent yl )bcnzo(g)pleridine-

2,4(3H, IOH)-dione

7 .8-dimethyl-la.( I ' -D-ribityl)i_lloxuine

376.:n

Content nOt len than 98% on the anhydrou s btsis

',% om 328 It

E

CI 444 nm in aqueous solution

Yellow to orange-yellow crystalline powdeT. with Ilight odour

The ratio A1..}A ... , is between

0.31 and 0.33

The ratio A..jA ... , is between

0.36 and 0.39

Muimum in waler aL Q 375 nm

IUI2(l beLw~"t''' - I !S· alld - !4O. in a 0,05 N $Odinnl hydroxide solution

D

NO! II>OIl' than 1.5'A> .f1l'r dlying al 10S· C foI4 hI'S

NOllnore Ihan 0.1%

NO! morr than 100 mglkg (<:-• .!culale!! 11$ anili .... )

NOl '""'" lhan J mglkg

NO! more lhan 10 mglkg

NO! more than ! mglkg

NO!lI>OIl'than I mglt.g

NOI more lhan 40 mglkg

Riboflavin-Y-phosphale Mldium

The~ lpe.:ificllions apply 10 riboflavin Y -phosphate logether with minor

amotinLS of f~ riboflavin II'd riboflavin diphosphate

lsoallo.azine

2Q4..988-6

Mormodium

(211.3R.4S }-5-(J') 10' -dihydro-7' .8' ·dimelhyl-2' .4' -dioxo·IO' -

ben;wj YI prcrid inyl)- 2.3.4- trihydrox )'J~III Y I pt>osphMe;

monosodium sail or , - -monophosphate eS\er or riboflavin

C "H"N ,NaOJ'.2H,o

For !he dihydrate fonn

For!he anhydrous form

Conlenl rK>I less Ihan 95% tolal colouring mauers calculaLed as

C" H,.N ,NaO. P .2H,o

250al"j7Sllmin ~ueouJSQlulion

E , \11,

".

Y~11ow 10 oran~ crysulline h)'poscopK powder ... ,!h dip odour and I

bitler Wle

Tile fBI;" A,.,.jA .. , il t>eIWffn

o

.J(} a"d O.J4

The ralio A.JA .., is bd .. -een

O']S andO.40

Mllimilm in Wlt~r at ea 17.'i nm

Not rrII)I'I: than 8\11, (lOO"C . .'i hn in VlCllum o~r 1',0,) for ~ dihydl1llt

,~

Not TnOrr than 1,0\11, (calcu lated 11 PO,on the anhydrous ~is)

Riboflavin (f=)

Riboflavine diphospba~

Not rrII)I'I:!han 69(,

Not TnOrr tlLan 70 m&fkl (cakula~ •• aniline)

Sot.....- than 3 m&fk..

Not mort tlwl 10 m&fka

i'\ot mo~ than I m&fk.

CI Food Y~llow "

T lI1IUi rot consi >IS ~~§tn billy of triiOdi um 5-hydn)~ y - I .{ 4-.u I fORillOplrnylJ-

4-( w"~ny'azoH l-p)'ralolt-j-carooAy'alt: and silbsidiary rolourin.

mattcn IOIf1I1er .. ·ith sodium ct.1ondc andIOI" sodium ... Ifalr at the prineip.[

uncoioolM COmponwlS.

Tartrazine is described as the sodium $lilt, The taltium and lhe potassium

aaJL II/"( alto permitted.

Monoazo

19140

217-699-5

T ri socii U I'll· Soh ydro~ y - I -{ 4-5 UIrOIllUOpllt n yl)4-{ 4·su I fonalOphen y IlZO t- H_

pyn.zok.l.camol ylall.'

S34,)7

ConlCnl not less than U .. total colouril'll maltcn cak\lllllCd as the IIOdiUIIt

&all

Ii , ..

SJOatca 426nminaqueousllOlution

I~

Maximum in water at CIo 426 nm

NO! ~ Ihan O.n

Not ~ IIlan 0,01'10 (calculah:d as anilinc.)

Not mo~ Ihan 0,2% under neulral conditions

Not more Ihan 3 mglkg

Not more IIlan 10 mglkg

Not mon: than I mg/kg

Not more tllan I mg/kg

NO! more lhan 40 mglkg

Quinoline Yellow is pn'parN by lu l(onaling 2·O.quilolyl) indan-I J-dione.

Qu iooli lll: Yellow consi.1i t ssc:nually o f wdium sal IS o f a millure of

di sul fonalu ( jlrincipall y). mol1O$ulfonales and triulf()llates o f the above

compound and mbsidiary colouring matten loge the, with sodium chloride

lUIdIor sodium sulfate as the principal uncoloUred componenu.

QuillOli"" YelloW is "'5(Cribed as the sodium ... It. The caieium and the

potassium sall:m alw prrmitled.

Qu illOphthalooe

47005

The disodiu m salIS of the disulfonates o f 2-(2..q uillOly l) in.:bn-I.3-dione

(principal COInpO<lerMJ

C"II.'" Na,O.S, (principal component)

477 J g (principal componenl)

. ,

Content not len Ihan 70% IOtal oolouring maile rs cal cu lated as the sodium

QuillOlilll: YellOW shall have the following composition

Of the total colouring mitten pre ... n!

loss Ihan 80% shall be disodium 2·(2·quillOlylJ indan-I,3-dione-

_

disulfonates

- not more than 15"" shall ~ sodium 242·quinol)'l) indan·1 J-di~­

monosulfona\cs

_ 004 '''''''' than 1M shall be uif(ldinm 1~2-quinol y l ) indan- I ,3.diooe.

trisulfonale

865 (principal romponenlj III ca 41 I IIIII in aql,lCOO S acetic acid solution

E 1%

"m

Muimum in aqurou. acetic sol Ulion of pH 5 at ca 411 nm

NO! R1OI\' than 02%

Not ~ than 4 .D'i1>

TOtal not rnon: lhan 0.5%

Not rnon: !han 4 mglkg

Not more lhan 0,01% (calcu lated as aniline)

Not more than 0.2% under neutnl conditions

Not more than 3 mglkg

NOI more than !O mglkg

Not more than I mglkg

Not mor<: lhan I mglkg

Not more lhan 40 mglkg

CI Food Yellow 3, Orange Yellow S

SUn5<'1 Yellow FC F comisl$ ns.enlial ly o f d isod ium 2-hydroxy-I-(4-

lul fooatopben)'luo) naphlhalene-6-l ulfonlte Ind . ublidiary colouring

mltttn together with sodium chloride andlOl' sodium sulfate as 1M principal

uncolou~ components,

Sunset Yello .... FCF is described as 1M $Odium 5111. ~ ("oJeium and the

potassium WI all' abo permincd .

'''''''

220-491-1

Disodium 2-h)"droJy-I-(4-sulfonalophenylaw) naphth al~ne-6-SlI I fonalc

C .. H ... "I,N·P,s,

4S2.l7

....

Conlenl not less than SS~ I0Il1 roIourinS matters calculated IS the itldium

SSS ~t c. 485 nm in aqueoul50lulion.t pH 1

E I""

10m

Muimum in .... 1IIon iii CI 43S nm 1\ pH 1

Not more than S~

T(llal not more than OJ'll.

NO! II>Ofe than 0/)1% (cak ulatN as anili~)

No! ~ than 0.2~ under ~ulral conditions

Noc ~!han J mglkg

NO! ~ than 1 mglkg

Noc more than I mglkg

Not rtl(lfe lhan 40 mglltg

Canni~s and carminic acid are oIItainoed from aqueous. aqueout alcoholic

or alcoholic: UU'aC1$ from Cochi~.I. which f;OflSiSLS of !he driN badin of

!he female insect t:JtKrylopilU l'OCCI/J Costa .

llIc colouring principl e is carmink acid.

Aluminium lakes of carminic acid (carmines) can be formed in which

aluminium and carminic acid are though!1(> be ~Knt in !he molar ratio 1;2.

In oommen:ial prodUC1S the colouring IJrinciple is ~Knt in auodatioo wilb

ammonium.cakium . potassium or Mldium calions , singly or in rombination •

.00 the$e cations may also be Ift$ent in exceSS.

CoItUTlen:ial products may alsooootai n proteinaceous material deri~ed from

Ihe ..,.,lre in5CCl . and may aisocoota.in mccanninale or a small ", .. due of

unbound aluminium cations.

Anthraquinone

'''10

Cochineal: 21 ~.6aO.-6; carminic acid : 2 I ~.(2)·3; carmi nes : 21 S.724-4

7 -il-I).. glucop)"!"lI/IOIO yl· J j.6 ..8·tctrahydnn y.j'l!rlhy I· 9 .1 O-<.IioxC*llhraoene-

2<arbolylic acid (carminic acid); carmine: is the hydrated aluminium choelale

of Ihis acid

492.39 (nrminic acid)

Cooten! not less than 2,1}% carminic Kid in theeuracuoontainingcatminic

acid; not Ie .. than 5O'l> carmi nic acid in tho chelates.

Red 10 dark red, friable, $Olid or powder. Cochineal Utracl is generally a

dark red liquid bUI can also be dried as I powder.

B 1.539

Muin,Ym in aq..eous ammonia $OIution.L ca ~18 nm

M""mum in dilulc h)'WochlQric soIution.L ci 4'14 nm for carminic Kid

CI Food RfdJ

,o\1Q1Ubi ... t'OIl$iits es sentially o f d,Kldium 4-hydl'Oly·J..(4-wlfonllO-l-

noph thyJuo) ~phLhale ... -I-.ulfonalc and subsidiary coIourin, mancn

to@clht:r with sodium chloride I nLllor JOdiunl sul fate ai LIM: prindp.1

uncoloUrN oomponenti .

AmnIbiM is describfd as lhe sodium sail. The cakium and lhe pcu.Ilium

salt are.llJO ~rmi~ .

14720

222-6~7-4

Di$Cldium 4.hydroxy·3-( 4· su l fooalO-l -naphthylaw) naphthalc ... · I ·sulfOll.1~

,"''''

Coment not leu than 8~'Io lOW coIounnllllllrtnl.cakulaltd.s the sodil.m

. "

E 1% ~JD ltcaSJ6nmin .. ue<MlOIution

I, m

Red 1(1 maroon powder or aranu1.-.

Maxinlum in "'aler al U St6 nm

NOI more than O~

Not more Ihan 2,0%

Not more lhan OIJI % (calculated ... aniline)

Not more lIwI 0.2 "" under MUtnll cooditionli

Not more than) mg/kJ

Not more than 10 m8fkg

NOI more than I mgfkg

Not more lhan I m8fkg

Not more than 40 mglkg

C[ Food Red 9

Amaranth consim essentially of uisodium 2·hydroxy- l-(4-sulrona~l­

naphthyllQo) lIaplnhalene-J,6.disulfonalC and subsidiary colouring maners

together wilh sodiu m chloride andlor sodium sulfale as the principal

unoolOllred components.

Amaranth is described as the sodium salt. l1le cakium and \he poIASsium

!.all are aI so penn i ned .

1618~

213.{l22·2

Tritodium 2- hydrol y- 1-{ 4-,u lfon310 - I -naphlhylalO) naphthalene-) .6-

disulfonate

C",H" N,Na,O .. S,

Content noIles.s than 85% total colouring rrWten , calcul:ued &$ the .sQdiun,

,.J>

E 1%

44OatcaS20nminaqueoussolution

'<m

Maximum in .... aler at ca 520 nm

Total not more than O.s%

Not IIIOI'e !.han 0 D I 'lo (cakulated as aniline)

Not IIIOI'e than 0,2% under neutral conditions

Not more than I mg/k,

Not more than I mglkg

CI I'ood Red 7. N~w Coccine

~ .. 4R ronr.,~ essenIially of Imodium 2.hydroly·I-(4-fulfOflalO.I.

Mphthylazo) Ntphlhl~nr-6.8~lsulfonooLe and lItbJidi.y coIouringllUllLen

LOg~'!lf:r with sodium chloride .nd/or sodium 1"lfau: as (!If: pri ncipal

uncolou~ components.

PonCUlI 4R is descriMd lIS the sodium salt . The no!eil/m and Ihe potassium

..... 1'""' aho po:nnined .

16VS

Trisodi u III 2-hydrol y. 1-( 4 •• ulfonato· 1 ·naphlhyluo) naphlhalene·6.8·

dUulfonale

.. ,

Con,"" noc IHs thin IIO'lt toW «Nouring mann1 .nok:u l&led.the lOdium

Reddish po .. "der Of ganuln

MuilllulII in ...... .., aI no SOS nm

T«al not more than 0..5%

NOI more than 0.0 I % (calculated as aniline)

Not more than O,2<l. under neutn.1 conditions

Not more than 3 m&lltg

Not more than 10 mg/k&

Not more than I mglltg

Not more than I mglltg

Not more than 40 mg/kg

CI Food Red 14

Erylhrosi ne oom ists eS$e nl iall y of di sod; u m 2-(2,4 S ,1.1<: tnUoOO- 3 -O~ ido-6-

oloxanlhen-9-yl) benzoate monohydnte aOO subsidiary colouring mall<:rs

together wilh waler. sodium chloride andfor sodium sulfal<: as the principal

uncoloured components,

Erylhrosi ... is described 1$ the $Odium sa)1. The calcium and the potassium

W I an: also permitted.

Xanthene

"".

Disodi It m 2·(2 ,4 ,5 ,1-te l raiodo-3-o~ido-6-oxoxanlhen-9-y l ) benWlle

monohydrate

CIIH, I,Na,o,.H,o

897.18

Content not less than 811\0 IIltal coiouri", manen.cakulalCd as Iht anhydrou$

sodium Nolt

E 1'1>

1 100 at "" 526 nm in aqut005 5OI",tion l1li plH

lem

Red powder or granules.

Description

Identification

A. Sp«trometry

Maximum in walCf at CD 526 nm at pll7

B. Red solulion in ... ·at...-

Purity

Not I1'I()re (han 0.1 Itt

Inorganic iodides calculated as sodium

iodide

Not ~ than 0,2%

Water insoluble matte r

Subsidiary colouring rn31ters (e~cepl

Not more than 4 ,D%

floorescein)

Not II'IOre tllan 20 mg/kg

FlUOl'eSttin

Organ ic compounds othn than

colouring maltI:TS

Tri·iodoresorciool

Not more than 0.2%

2 -(2, 4 ·dihy dr oxy-3,S-

Not~thMO .2%

d~nz:oyl ) benzoic acid

From I solution o( pH from 7 through 8. ~ ~!han 0.2%

ElMrextr:w;tabk mall....

uad

Not Il'IOre than 10 rngI'kg

Mercury

Not I1'I()re than 1 mg/kg

Cadmium

Not IIlCn than 1 mglk,

Heavy mrtals (as Pb)

Not II1OIl' t/\;In 40 mglkg

u k...

n.e hydrochloric acid inKllubk mac1ft' IlXlhod is

flO( appiiClbk.1t is repl~

Aluminium

by a sodium hydroxide insoluble matter. 31 rK)I more than 0,5'1>, for this

colour only

E 128 RED2G

Cl Food Red 10. AZQgffaRi lll'

Synonyms

Red 2G con,l,n essenti all y of disodium 8-acetlmido-l -hydroxy _2·

phenylal.Onaphth.llene-3.6-dlsulfonalc and subsidiary colouri ng maLlers

together with sodiUm chloride Indlor .odium $ulf'Ie al 1M principal

uncoloured components_

Red 2G is described aslhe sodium salt. The calcium and the poW.ium sail

are also permitted.

Monoazo

18050

223-098·9

Disodium I-lICCtamido-l-hydroxy-2-phenylazo-.... thak-ne-3 .6-disulronalC

C"H"N,Na,O,S,

Con~nt not less than 8O'lI> lOW oolooring matters. calculated IS the sodium

,.,

,= 620 at ca SJ2 nm in aqllOOU' solution

E 1%

Red powder or granules

Not ~ than 2,O'lt

N« ~ than 0.01 ... (calculated as aniline)

Not ~ than O~ \I~r neutrnl conditions

Nac ~ than I m&fkl

CI Food Rfdl7

Allura Red AC ~,ill1 eSW'ntially of difOdiurn 2-hydroay - H2·"",lholy·5-

melhyl-4-lulfonato-pMnylaw) naph(halr~·6-sulron'le and subsidiary

coIourin,

mauen lOIeWl' with JOdium chloride and/or sodium lulf.~ a$

1M prindpal un<:oklurN romponenu.

Allura Red AC isdeKribrd as the sodium salt. The cakium and tM pouuium

JaIl.., ~IIO prmuucd.

MollC>al.o

1603~

247·368-0

Di l od ium 2-hydrolY- I -( 2'_lhoa y-5-methyl-4-lulfonllOpMnylazo)

naphlhal~-lHulfon.alt

4%,42

. ,

Conitn\ no! k'" lhion 85.,., IOlaI ooIourinl maUn1. calcul ated as lilt sodium

Mll,lImUm in wotn aI CI. ~ nm

Not more than 0.2%

Not more than 3~

Not n\Qr<: than 0,3%

Not ~!han O.N>

Not mor<: than I j)%

Not _

than ODl% (<.:aIculated as ani lill<')

From a solution of pH 7. not /00", tllan 0 .2%

Not _than 3 mgJ\g

Not more than 10 mgIkJ

than 1 mglkg

Not _

Not more than I mgJ\g

Not more than 4{\ mglkg

C( Food Blu~ 5

PI"' nt Blue V consi StS esse ntiall y o f !he calcium or sodium a:>mpound o f

(4-( !l -( 4 - di ethy lami nop h enyl)-S- hyd ro~y- 2.4 -dilu lfoph e ny1 -

methylidell<')2j-cyd~~adjen-l·y1i<k1l('1 diethylammonium hydro~ide

inner sail and Sltbsidiary colouring maIlerS together with sodium chloride

and/or sodium sulfate and/or calcium sulfate II the priTlCipai uncoloum:l

componentS.

"The pou.u ium salt is aI!jO permitted .

Triaryhnethan!

42051

222-S73-8

"The ca lcium or sodium compound of (4 -(a-(4 -oiielhyJaminophenyIJ-S-

h)'dm~ y_2,4-di$ul fophenyl-m ethyl idene)2 j.cyclohe xidien-I_ y Jidene (

dlethyl-ammonium hydro~ide inner salt

Chcmic~1 fomlPla

Cakiunl r;ornpound: C" II " N,o,s ,C, ,,

Sodium compound: C"H" N,o,S,NI"

CIIkium compound: j79.72

Sodium compound: j82.67

.. ,

Con~t not leu than 8.5.1OIA1 ooIourin, malkn.ull."lliated .. tilt sodium

Muimum in water -' 638 nil' aI pH j

o. 01..., solution in_~

I'Iarily

Subsidiary o:o\(Morina matICn

Oraanic compounds Oilier than

roIourina ll\at:kn

J-h)·dro. y bellUldeh)"dr

3-hydro.y benzoic acid

3.h)"dro~y"",,·Julf~llloK acid

N ..... -dicthylamino benzcne su lfonic

~"'

No! ~ than OD I'Jo (nkuLa~ &$ ani1;'w)

UniulfONlW primary aromalK I minn

From' solution of pH S, not ~ than OJ"

Ethtr utraclllble mattcr

Not ~ than) mJll;.,

Ancnic

.....

Not1l"OOR than 10 malki

Not ~ than I rnJll;.,

Udmium

Not nlO« than I rnJll;.g

_tal.

Htavy

( &$ PIll

CI Food Blue 1

Indigotine consisu cmntially of a mixUlIt' o f di50dium 3,3 - dioJl~2,2 - -bi-

indol Y lidene-5 j" -disu I fooale. and disodi um ) J - -dioXG- 2.2--bi-indol Y I Kiene-

S,7' -di $u lfonale and JPbsidiary colouring matters tog~ther w ith lOdium

chloride and/or sodium sulfate as Ille pri ncipal uncoloured components .

IndigcMine is described IlS the sodium salt. The cakium and Ihe potassium

IoIIt_ abo permiued.

Indigoid

7lOiS

2 12-728-8

Di50dium 3,3' -dHIxo-2.2" -bi-indolylidene-5j" -disulfooate

C,.H,N, NA,o,S,

"',.

Cont.enl not leu thin 8S'" IOCIIl ooiouri n, malleB, calculated IlS the sodium

"',

...

disodium 3,3'-dio l O-2 ,2 -- bi-indolylidenl:_$T-di,ulfonatc: not more than

E I'"

480 at a.610 run in aq .. cou . . olution

I,m

Darit-blue powd~r or granules

Maximum in Wiler al ca610 nm

Not more than O.2'll>

Excludi ng di.odium 3.3 --diOllO-2,2 ' -bi .i ndolylidcne-5,1 · -<litu l fOftale: 001

more than 1,O'i&

Not more tllan 0.0 I ~ ("Iculaled as aniline)

Not more than 3 mJlkI

Not more than 10 m&fk&

Not more than I mJlkI

Not IIIIft than I mJlk&

CI Food BII,II!: 2

Brilli.,,1 Blue FCF con,ist' essentially or disodium 11-(4-(N-tibyl-l-

,ui fona.obenxy 11m; no) pile nyl )-il-{ 4_ N -e tb yl- J -sill fonalObenzyllmino)

cydoheu-2,S-dienyliOme) W>l1II:ne+2+$11lfona1e and iu llOlneR and IUbsidirry

roiourin,lIIIlW'n IOFthrr with todium ehloridl: and/or todium IUlf* II

the prindpil ullC(lloortil components.

Brilliant Bille FCF is dacribN IS the: 5O(\ium WI. The c:akium and me

pot.llium wt Il!e aho permitted .

Triill)'lmcthane

42090

223·339·8

DiJOd i u m 11·(4-( N -ethyl-3-su I ronatobenz yl amino) phtnyl}-o.-{ 4-N -ethyl-)-

'II I fonalOhenzy I ami no) c ydone ~ 1-2 ,5-<1ienyl i\kne) loll,ll!: ne-2 -iU I rooale

792.84

Content not Ies.s than 8~'" IOl&I a.>lourin, matters. calculMed as the $Odiu.

U/.

RMdish·bl ue powder or granules

MlU imum in water al ca 630 11m

N<)I more than 0.2%

N<)I more than 6,0%

N<)I more than Ij<l&

NOt more than OJ<l&

NOt more than 0,0 I 'lo (calculated as aniline)

Not more than 0.2'10 at pH 1

Not more than 3 mgiks

Not more than 10 mglkg

Not more than I mgik,

Not more than I mgiks

Not more than 40 mglkg

CI Natural G=n 3, Magnesium Chlorophyll. Magnesium Phaeophytin

Chlorophyll. are obc.oined by solvent ellraction of nalUTilI S!i1li ns of edible

plant material. grass. lucerne and netlle. During the subsequenl removal of

solvent, the naturally present co-<:>rdinated magnesium may be wholly or

partly removed from the chlorophyll! to give tile corresponding phaeophytill'l .

T he principal colouring matters all' tile phawphytin s and magnesium

c hl orophy ll s. Tile ex tracted product. from which the solve nt hu been

a.

Il'nlOVed, contains other pigments such

carotenoid. as well as oi ls, fats

and waxes derived from the soorce material. Only the following solvents

may be used for the extraction' acelone. methyl ethyl ketone.

dichloromethane. carbon dioxide. methanol.ethanol. propan·2-o1 and r.eune .

Porphyrin

75gl0

Chlorophyll,: 2 1 S-8OO-7. chlorophyll a: 207-5)6.6. Chlorophyll b: 208-:m.

,

'"'" major colouring principles are

Phytyl (I ) ' R . 175 . 185)-)-( 8 _ethyl _1 ) '_ methol ycarbon yl-2.7 .12.1 S.

tetramethyl- I) --o10-3-y;nyl·1 )'- 1 ) ' -17 .I8·te tlllhydrocyclopenta jl tl'

porphyrin_17_yl) propionate,(i"heophylin I). or., ~ ml3nesium complu

(Chlorophyll a)

Phytyl (l)'R .17S. ISS)-)..(8-ethyl-1 fonnyl-13'-metlloxycamonyl-2,12.1 a.-

Ir; melhyl·I)· '010-J-Yi nyl-I 3 '-13'· 17 • I 8-tetrl/lyorocyclopentl Iltl-

porphyrin-l7-yl) propiooale . (Pheophytin b). or IS the masnesium compln

(Chlorophyll b)

Chlorophy ll I (mag~5ium compkl): C .. H.,MgN.o.

Chlorop/lyUI: C .. H,.N,O,

Chlorophyll b (magnesium complex): C .. H,.M,N.o.

Chlorophyll b: C .. H..N.o.

Chlorophyll I (magnesium complu): 893.!i 1

Chlorophyll.: 87 1:n

Chloroph yll II (magnes ium complu): 907,49

Chlorophyll II: 81U,20

Cootent o f IOtaI combined Chlorophylb and their magne:si um oompleus "

n.ot kss than l()<ll,

E 1%

700 alea 409 nm in cllIorofonn

>om

Wuy $Olid f1\IIgin, in colour from olive green to dart. F n dependin'OII

the content of c(H)l'dinated magnesium

Muimum in c hloroform at CI 409 nm

Acet"""

Methyl ethyl ketone

Not more than 50 mgikg, singly or in combination

Methaool

E_'

Propan-2-o1

Huane

Not more than 10 mglkg

Dichloromethane

Not more than 3 mgfkg

Not more than 10 mgfkg

Not more than 1 mglkg

Not more than 1 mglkg

Not more than 40 mgfkg

CJ Natural Green 5, Sodium Chlorophyllin, Potassium Chlorophyllin

The alkali &alts of chlorophyllins are obtained by the saponifIcation of a

solvent extract of natural strains of edible plant material. grass, lucerne and

""tile. The saponification removeS the methyl and phytol eSter groups and

lIUIy panially cleave the cyclopen\enyl ring. The acid groups are neutrali«<.!

10 form the salts of potassium and/or sodium.

Only the following wlvents may be used for the utraclion: acetone. methyl

ethyl ketone . dichloromelhane, carbon dioxide . methanol, ethanol, propan-

2..,1 and hexane .

Porphyrin

75815

287-483-3

The major colCHlring principles in their acid forms are

- 3-( IO-carhox ylato-4-eth yl- I ,3 .5 .8 -\e\I'aIMthy 1-9..,Ml-2 -vinyl phorbi n-7 - Y I)

propionate (chlorophyllin a)

3-( I O-carbox y I 3to_4 _e th yl_ } - form yl - I ,5,8 - ITi me th yl-9 -oxo- 2-

vinylphorbin-7-yl) propionate (chlorophyllin b)

Deptnding on !he ~grn: of h)'drolyli$!he cyclopetl~yl ring may toe ek-.~

with the resultant prodlJCtion o f a Ihinl carboxyl function .

Mag~sium complexes may a lso be pre sent.

Chlorophyllin a (Kid form)

C .. H .. N.o,

Ollorophyllin b (Kid form)

C .. U" N.o.

Chlorophyll;n.: !i78.68

Chlorophyllin b: !i92.66

Each may be iocreased by 18 dallonl if the cydopc:ntenyl ring ;s cleaved .

Content of total chlorophyllins ;$ not leu than 95"" of !he sample driro It CI

]00" for ] hoor.

E]<jII,

700 at ea 405 nm in aqueous solution at pH 9

I<m

E 1%

140 all:& 653 nm in aqueOlluolution III pH 9

I<m

Dan: 8"'en to bluc:lblac!c: powder

Maximum in lIqUQ)Us phosphale buffer It pH 9 It ca 405 nm and at ca 653

"m

A~

Methyl ethyl I;.etone

M.""",,,

NOII1"lOh! than 50 mgIkg.s;ngly or in rombination

Ethano]

Propan-2-o1

Hexarw:-

Not more than 10 mgfkg

Not It1OI'e" than 3 mgi'kJ

Not more than 10 mgJkg

Not more than I mglkg

Not more than I mglks

Not more than 40 mgfkg

B

CI N8tu,,1 Green 3. Copper Chlorophyll. Copper Phaoeophylin

Copper chlorophyll. an: obtained by addition o f • sai l of copper 10 the

sub5lance obtained by solvent utrac:tion of natu,,1 mains of edible plant

ma~rial. g" " , I"","",. and nellie. 'The ~uct , from which t~ ",I,'em has

been rem.wed, conlains other pigmenls. such as carotenoids as well as fals.

aOO waxes Ikrived from the $OUr« ma~rial . T~ princi~l colouring mat"'rs

an: the copper phaoeophytins. Only the following solvents may be used for

the u traction: acclone , melllyl ethyl kelOne , dichlon::lmetharoe ,cart.>n dioJlide ,

methanol ,ethanol. ~ -2-o1 and heune ,

Porphyrin

75815

Copper chlorophyll.: 239-830-5; copper chlorophyll b: 246-020·5

[Phytyl ( 13' R, 115, ISS )-3-(S·e lh yl· 13'· methoxyclrbonyl-2 ,7 , I 2, I g.

le tram ethyl_13' -oxo_3_v;nyl_ 13'· 13 1_1 7 ,IS-tetrahydrocyc lo penta [al )-

porphyrin_17_yl) propionau:] copper (II) (Copper chlorophyll . )

[Pb)1yl ( 13'R.l 7S.l8S}-3-(S..,lIIyl-7 formyl-13'· methoxyearbonyl·2,12,IS·

Irimethyl -I 3' 'OKo- 3· vi nyl- 13'. 13 • 1 7 , I S-le trah ydroc::yclopellla raIl·

'

porphyrin-l1-yl) propionate] copper(!\) (Copper chlorophyll b)

Copper chiorophylll: C"H"Cu NP,

CoPl"'r ch lorophyll b: C,.H.,Cu NP.

Copper chlorophyll a: 932,75

Copper Chlorophyll b: 946,73

Con",nt o f lOla! copper Chlorophyll s is not less tIlan I O~

E 1%

S40 at cl 422 nm in chloroform

'om

JOOalca652nmin chJoroform

E l'lo

lorn

Wax y whd ranging in colour from blue g=n 10 dark grttn ~pending on

the wurce mall:rial

Maximum in c hloroform at ca 422 om amI at ca 652 nm

Acetone

Methyl ethyl ketooc

Not more than SO m&"kg,linsJ)' or in combination

M"""'"

....."

Propan-2~1

HCA_

Oidlloromethane

Not more than 10 m&"kg

NO! IIlO!'e than ) mgIkJ

NO! IIlO!'e than 10 mglkg

NO! more than I mg/kg

Not IIlO!'e than IJl'l> of the total copper phaeophytins

Sodium CopperChiorophyllin, Powsium Copper Chlorop/l)'lIin, CI Naw'"

Green 5

The l ikali !.aIlS of copper chloroph)'lIins ~ obtained b)' the addition 01

copper 10 the product obI&ined b)' the saponifICation of I solvent utnctioa

of natun! strains of edible plant I1UItmal. gnu, IlICernt,.,.;I nettle; the

saponi fication re moves the methyllnd ph ytol ester JI'OUpI and ma), partially

cleave the c)'ctopenk nyl ring . After lIddition of cop~r 10 the purif.ed

chlotophyllins. the acid gtoopll/'e neutralized 10 form !he WISor potassium

and/or lOdium.

Onl)' the following IIOIvmlS ma), be used for !he eUl'Ktion : acetone.melhyl

ethyl ketone. dichloromethane, carbon dioxide methanol, ethln!)], ~

2.01 and henne .

Porphyrin

75815

The majorcolooring priroc:iples in their acid forms are

H 1 o..C.rbo~ yllto-wlh),I·1 .J,."i ,8.tetnr.meth)'I-9~Ao-2-vi n)'lphortlin-7-

),I)plopionlte. copper complex (Copper chloroph)'lli n I)

"'"

J-( I o.cllrbo~ ylalo-4<d1y f. 3-rormy I· I J .8 -tri~ yl-!kI~o- 2 -vinyl phorbin-

7-yl)propionate.copper complex (Copper ehlorophyllin b)

CopperdllorophyUin . (acid form): C,.H.,Cu N.o,

Copper ehlorophyllin b(acid form): C,.II.,Cu N,O.

Copper ehlorophyllin . : 640,20

Copper : hlorophyllin b: 654.\8

E.Io<;h may be iro;reased by 18 daMns if !be: cydopenlcnyl ri nl it deaVfll .

u.... 9Yoro of !he sample

Conlcnl of lOcal copper rlIbophyUins i. not leu

dried al 100*C for I h.

E I ~

,= 145 CI 630 nm in

&qUeOII' phosphl.1e buffer at pH 7 • .1

al

Muimum in &qI.leOUJ phosphale buffer at pH 7 . .111 n 40.1 nm and 11630

,m

A~~

--

....

Methyl ethyl UIOno!

,

PIOpan-2-o1

Huane

Not 1IIOR!han 10 mllt&

Not more than 3 mt'kl

Not Il"IOft !han 1 mJ/kl

Not II"IOft than 200 IIIJI1II

Not mon: than 8~ oflhe IOC.Il copperehlorophylllni

CI Food G!Ufl4 . Brilliant G=n BS

Green S consists esse ntially of sodiu m N-I 4-(dimethylamino)pMn y1]2_

hydro~ y_3 .6-d i$ul fo- 1 -naphlhaleny)melh yl ene l-2.s-cydohe~ ad ie n _ l _

ylidene1-N-melhylmeth:m:mlinium and subs idiary colouring mitten IOgether

with sodiu m chloride and/or sodium su lphate .... the principal unoolou red

compounds.

Green S is described as 1M sodium sail. TM calcium and the poIassium sah

_ also pennined.

Triarylmethane

221-4(19· 2

Sodium N-14-11 4.( dim ethyl am i no) phenyll{2·hydro x y·3 ,6·d i, ulfo_l _

naphlhll e nyl )_ me t hy lene 1-2 ,5 · cydohexadien·l -y!lden e J- N-

methylmelhanaminium

Sod iu m

5-1 4 -di me lhylami no-(l.·{ a-dimet hyl; m i noc yC!o hell-2..s.

dicnylidene ) ben~yI J -6·hydroxy.7_$UI (onllo- naphthllene·2_nl fonlte

(alternalive chemical name ).

....

Cootent 001. less than 80% 10l.oI colouring mailers calculated as the sodium

,= I no al ca 632 nm in ""IUCOIU solution

E I %

Om blue ordarlc ~n powder or granules

Muimum in water al ca 632 nm

NoclTlO!l' Illan 0 .2%

Not man: than I ,O'l.

1'101 more than 0.1 %

NotlllOl"e than 0.1%

Not more lh3n 0,2%

Not more than 0.0 1% (cakulated as aniline)

Not more than 0,2% under neutral C()nditions

Not more tI\an] mglq

Not more than 10 mN

Not more !han I mglt.g

Not more ttum I mglkg

Not more !han 40 mglkg

Plain caramel is prepared by the controlled Mat treatment of carbohydrates

".de

(romme~ially ayail.bi,

food

nutritive I Wfttenc:rs whkh all' the

monomers &I11COSC lind fruclOse and/or polymers thereof .e.g. glurose s)TUps.

suc:rose.llM'or inven l yrups.1nd dellJtM). To ptQmOIC: canunelinUon.ao::ids.

alkalis and salts may be employed. with the ex ce ption of ammonium

compound~ and ~ulphite s.

2)2435-9

om; tiro".., 10 black liquids or iOlids

Not more than 50%

Not more than ~

0 .0 1 - 0 ,12

Nol more thWl 0,. %

NO(!IIOn: than 0 .2'1>

NO! more than I mglkg

NO! rn{)r'e than 2 mglkg

No! more than I mglk,

NOI more than I mglt.g

No! more than 2S msftA

Call,1ie sUlphite caramel is pn:p~ by !he conln)lled heal lrCatmenl of

carbohydrates (commeltially .vailable food grade: nulriti~ SWffltnm which

are the monomers g1~ and fruclOSoe &ndIorpolymers thereof,e., . &I11COSC

1)nIp'. suc:rose, and/or inven syrups, and dextrose) witb or without acids or

alkali., in !he prftCllCC of su lphite C(lmpounds (. ulphurou l l(:id, pOlan ium

lu[phil(', potassium bilulp/lilC . sodium I "[pllite and .odium bisulpttilC); no

ammonium rompounds are uK<! .

232435·9

Dark bro" .. " 10 blK!; liquids or solids

OM -0,13

NO( more than O.3'il1 (')

Not more than 0.2% ('l

0.3 - loS"" (')

19 - 34

Greater IhM SO

""-,,, io ~ . " _ 0 1 . 0.1 '11' rwi'lJ ooIutiooo of C'OfMOricaleJur: ....... i . .. _ ill. 1 <tII «II .. 610 ......

(') ~ . . equivaIenI_boo;. i ~. io.~ in ....... of. prooNo.1 IIa.-t"' . <fIIour ...... i'y of U.1 _ - . . . ""il> .

B 1.561

Not I1'IOI"e than I mg/kg

Not ~ than 2 mg/kg

Not ~ than I mg/kg

Not I1'IOI"e llian I mg/kg

Not more lila" 25 mg/kg

Ammonia CI.rBm~] is p,~par ~d by lhe controlled heat t,eatmf n t of

carbohy~s (com mercial]y available food grade nutriti"" sweeteners which

an: the monomers glllCOSe and fructose andfor polymers thereof, ~.,. ,11ICOSe

')TUP!, sucrose, andIor inve" s)TUP!, and de~trose) wilb or without 1ICid!l or

alkali •. in the presence of ammonium compounds (ammoniu m hydroxide,

ammonium carbonat~, ammonium hydrogen earbonate and ammonium

phosphate); 110 sulphite compounds are used .

232")5·9

Dark brown 10 blac:k liquids Of solids

than S09It

Not _

~ tIwI S09It

ODS-O.36

Not ~ than ]0 mg/kJ(')

Not more than 0,2<1. (')

0,7 _ 3.3'10 f)

13 - 35

Not more than I mg/kg

Not more than 2 mg/kg

Not man: than 1 mg/kg

P) C. - -.0, "dWn«I .. lII<~ oI'oO.!t. (" ,..) oal",ionor~........t """"'" oalidl in ""Mer in. \ ern cell 0I6tOM • •

f') Ea~ 000 """i • ...."riu ...... i ~ . io ... ~ in "',.". of."..,... ... ,,"vi ... coIOIII" inltnoiIy orO.! _

NGI more than I mglkg

Not more than 2$ mglkg

r-ood Black I

CI

Bri lli an t Black BN consists esse nti ally of tet rasodium -4-acetamido-5-

h ydrox y -617 - so I FonlI0-4-( 4 _s u I Fonatop he ny I aw)- I _n3 phlhyl alO 1

naphthalene- I ,7-disulfonale and subsidiary colouring millers together with

l odium c hl oride andlor sodium su lFate as the principa l un coloured

compono:nu.

Brilliant Black BN ii df:..:ribed as the sodium salt. The calciu m and the

poWoSium sal t are also permitted .

Bisaz.o

219-746-S

T e tru odiu m 4- acetamido- S-hydrox y-6/1 -su I fonato· 4 -( " '511 I ro n ato-

pnenylll7.O)-l-napblhylaro] napbtlLaJene- l .l-dis ulfonale

867m

Conlt:nl not less than 8O'A> IOIaI colouring IlUlIlen cakul~ as the lOdium

•• J<

Black po .... der or uanules

Muimum in .... ater al CI. 570 nm

NOI m<mlhanOl%

Not ....,;n than 0 D I'l! (cak:1l111ed as aniline)

Not ~ IIwI 10 ml!lkJ

NOII!I()I'e than I m&lka

VelC1.b~ cllrbon it produud by lhie carbonization of Yef;etable mau,riII

IlICh M wood. cellulose residlJel, put and CXlCQnUI and Other 'Mil' , 'The

noW malrrial is cartloniad at hi&/! \cmpnalU~l. II comiSlS esKntiaUy 01

(indy diyiOrd c arbon. II In.yconUlin minor amounlSofnilrOgen. hylWpn

. nd oly,en. Some moi'lure m.y be .b,orbt:d on the product .flrI"

..... lII'f .

~r

21S-609-9

lUll

Conle"l noI leu dun 9591. of cartIon nl~l~ on an anhydroul..-.d as!>-

f= b"i,

Insoluble in water and o rganic iiOlve nts

W hen heated 10 redn.: n il bums slowly withOlit a n ame

Not more lhan 4 .0% (ignilion tempenllu~: 62~°C)

NO! more lkan) mglkg

NO! more tIwI 10 mglkg

NO! more Ilia" 1 mglkg

NO! more tlwl 1 mglkg

NO! more lhan 40 mgI1:g

The extract obtained by extraclion of 1 g of the product with 10 g pu~

cy<:loheune ;n • rom;nuous e xtraction apparatus sllal1 be ooIourless. and

the nlKRS«'nce of the extract in ullraviolet lighl shall not be more intense

than lllal oflilolution of 0.100 mg o f quini ne wifate in I 000 ml of O.QI M

sulphuric acid .

Not nlOre lhan 12% (IW"C. 4 hrs)

The fihrnte oblained by ""'iling 2 g of the sample with 20 ml 1'1 sodium

hydroxide and fi ltering shall be colourless

Cl Food Brown I

Brown FK co,,,islS essentially o f a millUn: of

I

sodium 4-(2 .4-diarninopbenylazo) benlenesulfonate

II

Kldium 4-(4.6-diamino-m·lOly lazo) benzenesul ronatt

III disodium 4 .4 ' .(4.6-diamino- l .3-pn.nyienebisaro)di (be~ene.ulfonale)

IV disodium 4 .4 · (1.4-diamino-l.)·pn.nylenebisazojdi /bmzcnesuJ fOlt3iIe)

V disodium 4 .4 --( 2A·diamino · S- me t hyl_ I .)_phe n ylene b isuo)di

(bellRne.ulfonalej

4 .4 - A -- -f 2 A -d i am i nobenlene_ I .)., -Irisuo IHi -

V I tTi .odi u m

fbenzenewlfonalel

and wbsidiary colouring matleTli lO~ther ... ·ith ... ·aler. sodium chloride and/or

sodium sul fate ll§ the principalunc:oloured componentS_

Brown FK is de!iCribed IS lbe sodium WI_ The calcium IIId the pogssium

salt ...... a]o;o permitted .

Aloia mi~wre of Il10I"I0- , bis- and muzo colours)

A mi~!Ure of

sodium 4-(2.4-diaminophcnylazo) berueneStilfOll.lte

wdium 4-(4,6-diamino-m-lOlylazo) benzenesulfona~

disodium 4,4 ' { 4 h-diamino-I J'phenyJ..nebisazojdi (be~liul fOl1ale)

di50dium 4,4-{ 2,4-diamioo-l J-phenyknebisazo)di (benzmesulf~)

di sodium 4,4 '-( 2,4· diamino·5-methyl-I,)·phenylenebi5lZO)di

(benzenes u 1 fonate)

V I triSodi u m

4,4 • ,4"·(2 ,4· di, mi no~nzenf-l .3 J-triuzo )tri ,

(be n unesu I fonate)

I C" H" N,NaO,S

II C" H"N,NaO,S

[[[ C" H"N.Na,o.S,

IV C"H" N,Na,O.S,

V C,.H"N,Na,O,S,

VI C~I I , ,N.NI,o.S,

I 31 430

II 328.33

[[[ '20",

IV '20",

V 534,47

VI 726J9

Content nolless than 70% toIltl colouring matten

Of the toI.aI colouring mallcrs prefoent !be proportions of the compo~

shall not ue«d

r 26%

II ,,%

,,%

IV 16%

V ,.,.

VI 16%

Red-brown powdorror granules

Not more than 0,211.

NO( more than 3 J%

Not more than 0,7'10

Not more than 0,35'10

Not more than 0,007% (calculaled a. ani line)

From a solution of pH7, no! more Ihan 0,2%

Not more than 3 mglkg

Not more than 10 mglkg

Not more than I mglkg

Not more Ihan 1 mglkg

Not more than 40 mglkg

CI Food Brown 3

Brown liT con,ists essentially of di,odium 4,4" -(2,4-dih)'droxy-5 -

hydrox ymethyl_1 .J -phenylene bisazo) di (naphthalene - \ -sul fonalel and

sut.sidiary colouring mailers lOgether with sodi um chloride and/or ~ul fate as

!he principal uncoloured components.

Brown HT is described as the sodium sail . The calcium and potassium salt

are aho perrnilled .

Bi,azo

224-924-0

Disodium 4,4' -a .4-di hydrox y-j-hydroxymethyl- l .J-phenyl."" bisru:o) di

(naphthalene- I_,u Ifonale )

C"H"N ,Na,o, S,

652.s7

COfllen! 1101 less than 70% IOtai colouring maners cakulatc-.:l as lhe sodium

,,"

403 al CD 460 nm in "'1lJeOU' <olution al pH 7

E 1%

km

Reddish-brown po,,'dcr or granules

Maximum in water of pH 7 at COl 460 nm

NOIInOI'e than O~

NO!. more than 0,1%

NO!. more than OJ) 1% (Clleulated as aniline)

NO!. more lllan 0,2% in I solution of pH 7

NO!. more than) mglkg

Not more than 10 mg/kJ

CI Food Ornng<: 5

M l~ed carotenes are obtained by soIvenl e~tmclion of natum) strail1$ of edible

planlll, carrolll, vegetable oils, grass, alfalfa (lucerne) and nettle .

The main colouring principle consists of caroICooids of which bcta-carotene

IC<:QUnlll for the major part. u-:r<aro"'ne and other pigments may be preselll.

Besides the colour pj~nts, this SUMWKC may contain oib, fau and WHe!I

natUIlIJly occuring in the source material .

Only the following 50h"enu may be used in the ulraction: acetOne. melhyl

ethyl ketone. methanol. ethanol. propan-2-o1. hu.ane . dichlotontetMM and

carbon dioAide.

Carotenoid

7~lJO

Content or catolentS (cakulBICd as Ik-ne) i. oot Ies. !han $ .... r-or

prodIIcts obtained by rAIlX60n of ~~lable oils: not less IhanO.2'l& in edible

,~

E 1% 2SOOl\C. 440 - 4j7 nmin cyclolle~_

km

Muimum in cydohu~ 11440 _ .51 nm and 470 nm -486 nm

""-

-, ...

Metbletbyl ketone

Methanol

1"ot rnorelhM SO manc,. sinalYor in

f;ORIbinauon

Hn_

"'"""

10.,

not mon: than

Dichloromethane

Not more than 3 mg/kg

Not more lhan 10 mg/kg

NOI more !han I mg/kg

MI more !han I mglkg

CI Food Oran~ j

These §pecitication§ apply prt<\ominantly to all trans isomer o f ~-carole~

IOJ!<'ther with minor amountS of other carocenoids . Diluted and stabil ized

preparations may have diffe~nt dsltrans isomer ratios .

Carocenoid

.,"'"

" 0·"6-6

S36,88

2SOO.tca 4j)- 4S6nm incydotw:~

E 1'10

lem

Maximum in cyclohexane at n 4S) - 456 nm

Not 1ll<Ml' than 0.2%

Carocinoids other than !karotene: noc ~ than ),O'lo of total colouring

'mmen

Not IIKJfe than) mglkg

Not ~ than 10 mg/kg

Not ~ than I mglkg

Not lOOfe than J mglkg

Not mo~ than 40 mglkg

CI NlUunl] Orange 4

Carotenoid

75120

Annatto: 2 15-735-4. annalto seed extract: 289-561-2: bixin: 23O-24g-7

6' ·Methylhydrogen·9~ -cis·6 .6' -diapocarotene-6,6' -dioat ..

Bixin

6' • Methyl hydrogen -9' -t rans-6.6 . -di apocarote ne-6.6 . -dioate

Noroixin

9"ci.-6,6' -diapocaroteoe-6.6· -dioic acid

9'-Trans·6,6' -diapocarotene-6.6' -dioic acid

Bixin

CZlH",O.

Noroixin

C,.H",O,

Bixin

394.51

Noroixin

380.48

Reddish-brown powder, suspension or solution

Bixin: muimum in chloroform al ca S02 nm

Noroixin: muimum in dilute KOH solution at ca 482 nm

(i)

Bixin i. prepared by the eXlraclion of the ouler coating of the seeds of the

annatto tree (Buo orel/oM L.) with one or more of the following solvents

acetone. methanol. hexane ordichloromethane.carbon dioxide followed by

the ",mova! of the sol,-en!.

Noroixin is prepared by hydrolysis by aqueous alkali of the extracted bixin.

Bixin and oorbixin may contain olher materials exuICu,d frum lhe annalto

"'"

The bixin powder contains several coloured components. the major single

one boing bixin, which may be pn:s.enl in booth cis- and lrans· fonns. ThemtaJ

degradation products of bixin may also be present.

The oorbixin powder contains the hydrolysis product of bixin. in the form of

the sodium or pota!;Sium salIS as the major colouring principle. Both cis- and

tran.-fonns may be pres.en!.

Content of bixin powders nOlless than 75% total carotenoids calculated as

bixin.

Content of noroilin powders 001 less than 25% total caroteooids calculated

as ooroixin

2810 al ca 502 nm in chloroform

Bi~i n;

E 1'1.

, <.

,~

,<.

2810 II ca 482 nm in KOH 5OItUion

E

NO! ........., lhan) mg/k8

Not........., than 10 msIQ

NO! more ItwI I mJl1t8

(ii)

Waler lOluble annD'" is prepared by n!rac1ion with aqUeoui alkali (sodi um

or potassium hydro~ide) of II ... OIlIer coatinS of tIw: littdl of the annatto IJa

(8m. o ... 1I1l1tll L)

Water soluble annatto contains norlIilin. tIw: h)'d"'I)~1 product of bi~in. in

the form of lhe IIXl$um or pOlauium wtS.&J tIw: major eolouri nS prirw;iple.

80Ih cii' and !ram- !Omit may ~ ,,",sent .

. ,=

E

2810atCl482nmin KOHsoIu!ion

Norbuin

NO! moft , han J mJlk8

No! moft tholn 10 mJ!k8

Not _lIwIl mJll<8

Not _

than I mglk,

NO! mon' than 40 mslks

Caps2mhin

5S4.8S

CapSOfUbin

600.85

Paprika utrnct: Willen! not leu than 7 f)% carolenoids

Capuntbillfcap$OlUbin: DOl. I~ than )()91, of IotaI carolCrooids

,to

2 100 al cI462 run in acel()<lC

'om

Daft-red "iseoul liquid

Muimum in acel()ne al ca 462 run

Gazzetta tal-Gvern ta' Malta — Avviż Legali 1997 199 — 199 tal-1997 – Regolamenti tal-1997 li jemendaw ir-Regolamenti dwar Kuluri għall-Użu fi Ħwejjeġ ta' l-Ikel

1J- O-gI\Icopynnosyl· 3 1>.8- LeInhydro:t y_l · melhyl·9, I O-dio:tQllllltt..:-cne-

2-carboxylic acid (.cwu karm iniku ): il-karminja hOWl l-hydraICd aluminium

chelw. ta' dan j.aCidu

492,39 (aCid " karminika)

Kontenal mhux ioqas minn 2.Q'1o ta' aCidu kannini ku n.cstratti Ii j kun fihom

aCidu karm iniku: mhu:t inqas minn SO'iI> ta' ~d ~ karminiku (K-chelaICs ,

Ahmar gila! alImarskur. frijabbli, IIOlidi joew tl1lb . Esll'all ta' cochinul huwa

itner.alment likwidu th mar skur iida jista ' jig; mniuef btlala ll'ab.

rrwsi mu f'soIuujoni akwejlo ta' l-ammon,. Ii ca SIS nm

Massimu f'soluujoni idroklorikadilwita fi ca 494 nm ghal ai:idu karminiku

Mhux it jed minn) mgJks

Mhux iijed minn 10 mglkg

Mhu~ iijed minn I msfk:g

Mhu~ iijed minn I mJl'ks

Mhu~ it jed minn 40 mglkg

CI Food Red 3

lrA1.DNbine jikkonsilti essellljalmenl rdisOOium 4-hydro~y-3-(4-sul fonato­

I-naphthylazo) naphthalene-l-sulfonatt u maler,ia kolon.nti l ussidjarja

f1imkien rna' klorur las-sodju uf)tw iOIfll w-sodju btIaIll-komponenti mhux

ikkuluriti prini;iplli.

L-Amrvbine huwa ckskrin bhala l·melh w-sodju: II-melh t.al -kaU:ju u tal -

pouuju huwa wkoll pertne5l.

14720

222.6S7-4

Disodiu m 4-h ydro~ y-3-( 4-wl (oolto- l -naphthylazo) naphthalenc:- 1-511 lronale

Cji,},},a,o,S,

lO'",

Kon~nu t mhu~ inqas minn SS% tal-maleria koJoranti totaIi, UlkuLaI brIaIa

I-melh IIs-sodju

E l ~m

SIOficaS I6nmrllOl.uzzpniakwejl

Massimu fl-il ma fl c. 516 nm

Mh ux iijed minn 0.2%

Mhu. iijedminn 2D'lo

Mhu. iijcd minn O,Ql'>' (kalkula! btlala aniline )

Mhu. iijed minn 0.2 % latH kondiujonijici

Mhu. i-,jed minn 3 mg/k~

Mhu. i.l:jed minn 10 mJlki

Mhu iijed minn I mg/kl

Mhu. iijed minn I mg/kl

Mhux iijed minn 4() mglkg

C! Food Red 9

L-Amaranlh ji ld.:onsi~1i ess.enzjalrnenl!i uisodium 2-hydro.y- 1 { 4-wlfooal()-

l_naphlh)·l azo naphlhalell<-3.6-disulfonale u materja koloranli sussidjarjl.

flimJr.icn rna· kIorur iaS-sodju "'jew sol falla$_~ju h!\alal-komJlO'le1lIi mha.

ikkulurili prin.,'ipali.

L-Amaramh huwI <kskriu bhala I-melh tas·sodju . lI-melh tal·taltju u tal·

potassju hawa ,,·koll pel1l1ess .

Monoazo

1618 ~

213-022-2

Trisodium 2-h ydroxy-I·( 4_s u IrOnalO- I . naphlh y law) naphthalene_} ,6 -

disulfonate

C.,H"N,Na,o,.S,

Kontcnut mhux inqas minn 85% tal·materja koloranti lotali. hlkulat bhala

E 1%

44Of,ca520nmfsoluzzjonial;weja

k,,'

T rab jew granuli kam-.ella harruani

Massimu ([ -ilma fi ca 520 nm

Mhux iijed minn 02%

Mhux iijed minn 3.0%

Total mhux iijed minn 0.5%

Mhux iijed minn 0.0 I % (hUmlata bhala aniline)

Mhux iijed minn 0,2% tarlt kondizzjonijid newtrali

Mhux iijed minn 3 mglkg

Mhux iijed minn 10 mglkg

Mhux iijed minn I mglk:g

Mhux iijed minn I mglk:g

Mhux iijed mill" 40 mglk:g

CI Food Red 7. Ne .... Coccine

II-Ponceau 4R jikkonsiSli es~nljal ment fi !ri$.Od;um 2-hydroxy-1-(4-

sulfonll~ [. n.'Ip!llhyluo) naphlhl lene-6.8..;1isulfonat.: u materja kolorantj

sussidjarja flimkien ml' klorur tas-sodju lllje .... soI fal las-sodju btIIla 1_

kompone:nti mhu~ iiduturiti prineip;1li ,

1I·l'onn-au 4R hU .... D deskritl btlala l_mtlh ta5-So)(Iju II-melh laI_kal"ju u tal-

polAS$j\I hu .... a .... koU permns.

16235

220-036-2

Trisodium 2- hydrox y·t-( 4-sul(onalo-I -n.phlhyluo) naphthalene-6.8-

disulfonate

Kontenut mhUl inqas minn 80% lBl-materja kolorvoti IOUti, kalkulat btlal.

I-melh tas .$.Odju

E 191, 430 fi ca S05 nm rtoluujooi akweja

1=

TflIb je .... granuli hamranin

Mluima n-ilma fi ca S03 nm

Mhux iijrd minn 02%

Mhux it jed minn l ,()<l(.

Total mhu. ii:jed minn 03%

Mhull iijed miM 0.0 I % (kalkulati bNla aniline)

Mhull it jed minn 0.2'l> la/'II kondiujonijiel newtl'llii

Mhull iijed minn J mglkg

Mhull iijed miM 10 mJl\&

MhUll iijed minn I mJl\&

Mhull it jed miM I mglkl

Mhull iijed minn 40 mA

CI Food Red 14

L-Erythrosine jjikkonsilli e5Senzjahmnl f disodium 2,.2,4's .7-~lrIiodo-3-

ollido-6-olloxanthen-9-yl) bentolle monohydrate u materja ko loranti

sunidjarjl flimkien ma' ilma. klOl'llr laH odju u/jew solfatlls-sodju btwal-

komponenti mhUll ikkuluriti pri~ipali,

L-Erylhrosine huw. Iie$krill bhllil-me!h LU·sodju.lI-melh tal-kaJi:ju u tal-

potalSjU huwl wkoll penroess.

",,.

240-474-1

Di sod ium 2-(2.4,S.7-te lraiodo-J-olido-6-01ounlhen-9-yl) benzol~

monohydnlc

897.81

Konlcnu\ mhull inqas minn 17% u l-mateTja koloranti totaJj . kalII:ulll bhaJa

I-melll IMidoi taHodju

£ 1'10

II OOfica52'6nmrllOlllZZjcniakwrjo lipU7

1=

Tnb jew panuli 1'Iomor.

Mauim u fl·il ma Ii ca 526 nm Ii pH7

Mhux il:jed minn 0.1'10

Mhlu iljed minn 0.2'10

Mhux it jed minn 4.1)'1,

Mllux it jed minn 20 mA

Mhua ii:jed minn O.2'lo

Mhux il:jed minn O,No

MiM lOIuujoni taO pH miM 7 ... I . mhux it jed miM O.2'lo

Mhua iljed minn } mA

m"'"

Mhul iijed min .. 10

Mhul ,I:jed minn I m&lk,

Mhua itjl'd mIn" I m&lk,

lI·mnodu ta' maltrjol i ma. tinl'lall. fl -.kid u idtokloriku rna hua appliubbli.

Japplib minfloku I·_todu ta' rnaltrjo Ii nul tinl'lall. fl·idrouidu c.lOdju .

rmhul akw minn Oj'lo ,hal dim il· kulu r bi n,

CI Food Red JO. Al.O&erat1;nt

L-Ahmar 2G jikkonsisti essenzjalment f di~ium 8-lI«lamido-l _ hydro~y _

2-phenylazonaphlhakn.e-3t>-dis ulfonale u mau: rja ko loranti sussidjarj a

nimkien rna klorur taHodju wje'" 5Qlfat tas-~ju btlala I-komponenti mhu~

ikkulurili prini:ipali .

L-Ahmar 2G huWll deskritt btlala I-melll ta5-~ju , 1I-mc:11I ta/-kalcju u tal-

pota .. ju huwa .... koll pemJess.

18050

223..()98-9

D isodi U m 8- acelamido- J -h )'drox y-2 -phenyl azo-naphthale ne_ 3 .6-d i I ul fonate

C" H" N,Na,o,S,

509.43

Konu:nUI mhu~ inqas mino 80% Ial_mau:rja kolorami totali, kalkulal btlal .

I-melll tU-sodju

E J%

6X1lica532nmfiOlUZljoni ak'NC'ja

1~

Tr.b jew &nmuH homor

Mal1irnu n-ilrna Ii CI 532 nm

Mhul it jed minn 0.2%

Mhul it jed minn 2~

Mhux itied minn 0.0 I % (kal kulati bhala aniline)

Mhul ii:jed minn 0.2% tallt kondi zzjonijiet newlrali

MIIlIl Jtjrd lIIi"" 3 1II11k'

Mhux it;ro m;"" 10 IIIJI'Ii:I

Mhux iJ:jed lIIi"" I ml!'ll:l

Mllux it;ro minn I milks

Mllux iijed minn 40 mg/ks

CI Fuod Red 17

.... Ahm. Allura AC jili:li:omisli essenzjalmenl rdisodium 2-hydroxy- H2_

mclhoxy-S-methyH-MllfQfl;OiO-phcnylam) ~$U11\lnaIe u makIja

kDIoraIIli sussidjarja Ilimltien mII'li:Jorur IaHOdju "'jew IOIr~1 w-$Odju bhaIa

I-Ii:ompone:nli m!lul ,Ulliuriti prinCipali .

.... Allmar AlIura AC hllWI desli:rin bhIlll-melllllHOdju. lI-rntlll UII·ultju

II lIl-patanj.llluwa ... ·koU P'" 1l1C!:U.

Mnnoazo

16035

Disodiu m 2-hydrol y-I-(2- mclhoAy -j-me thyl-4 ,slllro nl!Oplw:ny luo)

.1hakne-6-.ulf(ltLl1o

496,42

Kontenut mhUA inqas minn 8j ... ul ·materjl koknnli totaIi . kalkulal btIa\.

I·mellllas-sodju

»a nm rtoluujoni ak_ja Ii pH 7

E I'"

j40 fi ca

"m

Ttab jew panuli .... mar sll::ur

Mlni mu n · ilml fi ca S04 nm

Mhul it jed minn 3~

Mhux it,ied minn 0~1%

Mhul it jed minn 0).%

Mhul iijed minn 1.Mi>

Mhul it jed minn 0.0 1% (li.alkula!i bhala ani line)

Minn solu ujoni III' pH 7, mhul iijed minn 0.2%

Mhux it jed minn) mgfks

Mhul iijed minn 10 mgfkg

Mhul iijed minn 1 mgfkg

Mhux iZjed minn 1 mgfkg

Mhul iijed minn 40 mglkg

Cl Food Blue ~

L·J kha) PalCnl V jikkonsisti es~nzjaJmenl fil-kompost tal-kalcju jew sodju

[ 4 _( a- ( 4 -d ielhyl am i noph e nyl )-S- hydro l y- 2 ,4 -d is u I fo phe nyl -

I. '

me!hylidcnlC)2.5..:yclohcxadi en- l-ylidcne l dielhylammonium hydrolKk

inner ~ll u malerja kolOf1U1li suuidjarja nimkien rna' kloror las-sodj u uljew

solfa! tas-wdju u/je w wlfal tal-kaltju btlal l I-ko mponenli mhul ikkuluriti

priocipali.

II-melh tal-p<I\a.'sju hUlliD wkoll permc: SI.

Triarylmethane

4205 1

222-573-8

ll -kompo6llll ' bJCju je w sodju Ill" [4-(o.(4-dielllylaminopto.nyl",S-hydrolY-

2,4 -disulfophenyl-melhylidene)2 .5..:ydohuadien- l -y lidene [ d ielll yl-

ammonium hydroxide inner sall

8 1488

Fonnula ki mih

Kompou llMaltju: C"H" N ,o.,s,CI"

K ompo~1 las·sodju; C " II li N ,O,S,N.

Kornpou taI·Uk,..: .579,12

Kompcm u."'sodju: .s82.61

Kon~nul mhu~ inq:u m; .... 8.5'lt uj ·nulnja koknnli 1OIali. kalkulac bbill

1._1h taS-todju

E l'lt 2000 Ii ca 638 nm rMlluujoni IlI:.w~ja Ii pl~ 5

10m

~sl:.riujoni

Tmb FW S\VIuli la' ku]u. ,kl'lll] !il:ur

Ilknlifikaujoni

MlUimu n ·ilma 638 nm Ii pU 5

B. SoIuujoni kulur ikllal " ·il nu

Puritl

M3Ier,ill li m'linl'lall~ n·Uma

Ml'lu~ ilFd minn 0.2%

KOmPOSli orsanici minbarTa mllcT,ilI

koloranli

3-1'1ydrollY benWdohydc

3, hydro~y benwic Kid

Tota! mhul iijed minn 0.5%

3.hydrolly-4-sulfnnwic acid

N ;II-diethylamino benzrno: $ulfonic

ocid

Mh ul ii-jed minn 4.0%

Leuro base

Mhul "jed minn 0.01 'It (kalkulali btIala Imline)

Amin"UII)fTl3OO piilla,;; linn wlron.l

Iot.ctr';' n uaibbl i bl-c:lcR'

MilUl solu~i III' pH.5, mlMu iijed minn 0.2'lt

Mhux iijed minn 3 mgfk8

Antniku

M hH ilFd minn 10 mgfks

Comb

MnturJII

Mhu iijed mi .... I mJl'k8

Kadmju

Mhu l itFd minn 1 mgll:.g

Mwolli Iqal (btlal Pb)

Mhu iijed miflfl-'O mJl'k8

CI Food Blue I

L· lndigo!i ne ji kkons isti euenzjalmenl flalliita la' disodi um 3,3 ' dio~o-2.2 ·­

bj -i nOOIylidene-5 S - -disu I rona\('_ u d isod ium ),3 . ...uo~o- 2 2" -bj-indol Y I idene-

5 ,1' -disul fooale u materja kolonnti .... n idjarjl nimkien ma klorur !as-KW.Ij-u

ulje .... rolfs! la5-sodju bhala I-ko mponenti mhlll ikkuluriti jlriocipa li .

L-lndigOline h.I ..... deskrin bhal,l-melh las-KW.IjU . JI-rnel h tal-kalCju " LaI-

potalSju hu ........ l oU ~s .

Indigoid

13015

212-728.8

KOn\('nlll mhlll inqas minn 8~% tal_materja kolorami toolli. kalkulal bIlal .

j-rnelh lu-sodju

d ioodium 3 ,3- -diolo-2.2· ...bj -indolylidene-5,r -dio.ulforwe: mhUJ. ;ljed miM

IS<itt

.

,=

E 1%

48Olica610nmfooluujoni akweja

T",b je .... S"",uli kulur ikhal sku r

Mass;mu n -;Ima fi ca 610 nm

Mhux it jed minn 0 .2%

Esklul disodium 3.J · -dloxo-2.2· -bi·indo1ylidone-5.1" .(Ii,ulfo",lIl/: mhul itjfd

minn 1.0%

) Tool m_" It" m'oo OJ%

Mh u~ lJ:jed minn 0.0 ' % (kalkulati btlala aniline)

Mhux ltjed minn 0.2% tatn kon.:llzzjortijie! neW!rali

MhUl iijed minn) mglkg

Mh llx ii:jed minn JO mg/kg

Mhux it jed minn I mg/kll

Mhu x il:jed mi nn I mg/kll

C[ Food Bl ue 2

L-lkIlai Brillanti FCF ji kko nl isti essenzjalment fdilOdium (1.(4-(N~thyl-3-

I II lfonatobenz y 1 ami no) phenyl) -0.-( 4 · N -c t.b y 1- 3 -1111 fonat~ n y I am i no)

C)'dOMU-2 .s-dienylidene) 1OI~2-$I'\lronate II 1.i50men titgtlu u materja

kolornnti l uu idjalja nimkicn rna' klorur tas-sodju uljew &al fal tas-lOdju bfIala

l-komponenti mhul ikkuluriti prineipal"

L- Ikhal Bril1anti FCF hliWI destri n bl'llla I-mel h tat-sodju _ !I_melh taI-kali

ju II IaI-poWlju hu"", wkoll pmneu.

T riarylmethane

",,.,

223-339-8

DilOdium (l-(4-(N~thyl-)-lulfonalQbenzyJlmino) phenyl}-o..( 4-N-c!hyl-)-

IlIlfonatobmzylamino) c)'cJohua-2.s-dicnylidene) lOIuene-2-$I'\1 fONlC

792,84

Konte nut mhul inqa!; minn 8S% tal-materja ko loranti IOIali. kalkulat btlala

I·me lh taNodju

1630 fiCll6lOnmf5Oluujclni~ja

E 1%

I,m

Mas.timu fl-ilma Ii C111630 nm

Ml'lu~ itjIW minn 01%

Mltu ~ .tjed minn 6.0%

Mhu~ ii:jIW minn 1.5%

Mhux ii:jIW minn 0.3%

Mhu it jed minn jJ)%

Mhul iijed minn 0.0 I % (kBl kulati bl"lall anili"")

Mhul ii:jed minn 0.2% Ii pH 7

Mhlll ii:jed miM J mglkg

Mhul iijed mi nn 10 mglkg

Mhu;l iijed minn I mglkg

Mhux it jed minn I mglkg

Mhul iiFd minn 40 mglkg

lI-klQrofllli jinki$bu bl-filJaUjooi r'iOlvcnU Ia· ~ri nalurali Ia' marerjal

Ia' pj:lllti Ii jiniekJu.lmxi ~ .Iutc:m u l'Iurrieq . Waql iHnehhija slIssegwenti

1a$'$Olve m , il·manjesju ko-ordinal fil-pn: i:enu naturali tieghu jisla· jilne hha

kollu kemm hu jew panjalmen! mill-ldorofiJli biu jinghalaw iI-p/Iaeophytins

koni spondtnti . lI · ma!crji kolonnti prineipali lIuma l-pIIaeophytins II I·

magnesium e hloropllylls. lI-pn:xIott cstral!. Ii minnu jkun uv:hlla , -.nlven!.

ikun r,h pigmen!i o hra bllal ma huma carotenoids kif uk{)U zjut. xahmijiet u

XIlllla· denvati mill-materjal Ia· antini . Da" .... is • ...,I,-cn!i Ii jejjin biss jistghu

jintubw gI'Iall-cstnlUjooi : acelOM. methyl ethyl ketone . dK:hlorome1llane.

(arbon dioxide. methanol.ethanol,propan-2.o1 II ~xane .

?Qrphyrin

1~810

Klorofilli : 2 1 S-800-7 • Klorofillt a: 207-SJ6.6. Klorofilli b: 208-272-4

Phylyl (13 ' R .11S . 1 8S )-3-{8- elh yl- 13'-melhoxycl. bonyl- 2 .1.1 2 .Ia-

lelr.melhyl - 13· -o10-3· Yin ),l_ 13 '- 1 l '· l l.l a'lelrahydroc:),dope'li' r a11-

porphyrin - Il-yl) propionate. (Pheophylin a). jew bhalll-kumplcullJ_

manjesju (Chlorophyll.)

Ph),yl (13' R .17S . 1 8S}-)..{8~hyl -7 fonnyl-I l ' -melhol)":lrbonyI-2.12.1 S-

Ir; melhyl · l l · -010- 3-Y; nyl- 1 3'· 13'- 11 ,18-letrlhydrocyclopenl' r all _

potph)Tin- l1-yl) prop;orwc. (Pheophyti n b). jew blIIl. l·kumplns lIJ-

manjuju (Chlorophyll b)

Chlorophyll. (kumplcn lll ·manjcsju): C .. H,ftaN ,0,

Chlorophyll b (kllmplcss tal-manjesju): C"H",.o\1" ... 'O.

Chlorophyll b: C .. H"N,O.

ChioropbyU. (lnImpless tal-m""jnju): 893jl

Chlorophyll a: 811.22

Chlorophyll b (kumplcu tal-manjesju): 907.49

Chlorophyll b: 88S.20

ta&flhom

Kon~UI taoI-KIoror.tti k(llllbilllli lOUJi, I-kumplnsi tal-IIIMjesju

mhul inqas minn 10'1.

E 1%

',m 7OOfica409nmfichlorofonn

SoI~ blIIl uJJU! ' li jvarj.a rd-kulu. minn aI'Idar iebbup sllallllldar skU.

skond i1-konlrnullll-manjesju ko-otdinal.

Musi mu fi chlorofonn fi CI 409 nm

Skond ii-grad la' hydrolysi$, il-cycl/),.~nl~n)'1 ,/nlt jilta' Ji nferaq bil _

produujooi riiullanli la' lielel funzjoni kartIoslili .

Ji$lghu iitunu .... koll ~i:enli kumpiessi w-manjesju .

Chlorophyllin a (ghamla li:ida) : C .. H"N.o,

Chlorophyll in b (ghaml. atida): C"H.,N.o.

Chlorophyllin a: j78.68

Ch lorophyllin b: j92.66

Kull .... 1If\da IiSla' litdied bi 18 dallOltS ,ieitk il-rycloptnwlyl rinR jinfe ....

II-konlenul la'ldorofiliini totaJi mhu~ inqu minn 9S~ Iai-umpjun imniUd

fi ea 100" &hal skgha.

,<.

E I~

700 fi ca 40j nm rlOluzzjoni ali;~jlli pH 9

E l~m

l40fi ca6Slnm flOluzzjooiakwejlfipH9

Trab aI'Idar skur ghal ikhallilewdien;

Mlnimu fi pho$pltall: bufftr akweju fi pH 9 fi ca 40' nm u fi ca 6Sl nm

A~

Methyl t'lhyl kelOne

M, ......

"""""

Mhul iijtd lII inn 50 mJfks. watltdhom jew

Propan-2~1

rkombinaajoni

"',-

Mh\l~ it jed mmn 10 mgtq

Mhua it jed minn 1 m&fkl

Mtuu it jed minn 10 mA

Mhu it jed minn I mafk.

Mhua i!jed minn 1 mJl'k.s

MII"," it jed minn 40 mgi'k.

CI A1'Idar Nalurnli 3, Klorofil1a lIlr·Ram, Phaeophylin lar· Ram

II-klorofilli lar-r.lftI ji nki sbu bit-tkda u' melh lIlr'11Im mas'SUiIanZll miksuba

mill~tru~joni b 'solventi ta' teneri naturali ta ' malerjalla' pjanti Ii jiui~klu,

hlUC i~ , locem , U hurrieq , lI·pl'Ooou, Ii minnll jkun tneMa s·sol~enl, ihn fih

pismenli o hn bhal ma hllmacarolenoids kifukoll uh mijiel II lIlma' derivali

mill·maleTjalla ' origini. U·ma leTji t olonnl; prinCipali Iluma " phaeopllylins

tar· ram , Dawn i $-soI~nti Ii ;ejjin bin jiSlghu ji ntub w ghaJl-e~nujoni

kelOOe, melhyl ethyl ~ elOne, dithloromelhane, carbon dio~ide, methanol,

elhanol , propan ,l,ol II he~ane ,

Porphyrin

158 15

~rchlorophyn a: 239-8J()..S; copper chlorophyll b: 246-020·5

I Pll yly l ( I 3 ' R ,I1S ,] 8S )-3 ,( 8 -elhyl ,'3'- melho~ ycarbonyl -2 ,7 ,12, 1 S'

tetramelhy]·13 ' -o~ o-3· viny l · ] 3 '· 13'· 11 ,18-lellllhydrocyc]openlB ' 11/,

porpbyrin. 11_yl ) propionate) copper (II ) (Copper chlon:>phylll)

I Phytyl ( I3' R .\1S ,ISS)- 3.( 8-elhy 1·1 form y' " 3'· metho~ ynIbonyl· 2 ,12 ,I g..

Irimelhyl . 1 3 ' .o~o-3-v iny l · 1 3 '· 1 3'. 11, 18 -letrlhydrocyc!openta 111)-

porphyrin-11_yl) propionlte) copper (II) (Copper chlorophyll b)

Copper dllol'OphyUa: CHH"Cu N,O,

Copper c hlorophyll b: C",HIIICu N,O.

Copper chlorophylla: 932.n

Copper c hlorophyU b: 946.13

Kontenul la ' kloror.Jli tar·ram lOlIIi mhu x inqu minn 10'lIt

E ,-. ~ fi <;.I. 422 run fi mloroform

1=

E 1-. 3OOlica652runfidlloroform

1=

Solidu btIaI .lima' Ii jvarjl fiI·kulur minn ahdar bhlani shlllhdar "';ur

,kond il·mall:rjal la ' oriiini

Musimu Ii chloroform fi ca422 nm II Ii cI652 nm

Awone

Methyl ethyl kelOlle

Melhanol

Mhu~ ii,ird min" SO mg!ks. wahoedhom jew

"""""

rkOlllboinanjOlli

Propan·2-{)1

IIna...

Mh "~ ititd minn 10 mgll:g

Oi cll Ioromelhane

Mh .. " it,ird milln) mN

Mhu~ ii,ird milln 10 mgll:g

Mhul ii,ird minn J mg/kg

Mhux ii,ird minn I mg!kg

Mhu~ ii,ird minn 200 mg.lkg

Mhu~ ii,ird milln 8,o<ilt taI .phaeophylill5 tar·ram IOOIJi

Sodium CoppcrChlorophyllin, Potus'Uol Coppc r Chlorophyllin, CI Atldar

Nalurali S

ll.melh u,' I·al kal i u' klorofilli ni tar-. am jink.",b bit-tieda ta' I1lI11 mal ,

prodoll mi k."b bi5-laponifib t:zjoni la' eSlraujoni b'wlvenli la' ~neri

lIalurali la' ma~rjal \I' pjanli Ii jillieltlu, ha~iJ, lucem, II hurrieq; is·

$aponifihujoni _hili l-rSler groups ta' "",hyl II ph)'101 u hUll' panjalment

lofroq il-ryciopemrn)'1 rjMR , Warai-lieda 18 ' ram mal-ktorofillini purifibli,

il ·gruppi .cidi jitu newtrnliwlli bin jiffurmaw il-melll t.aJ·potaSlju wit ...

mju,

Oawn ''''$Oh'enli Ii ;'ejjin biu jistghll pntl/taw ghall~~'''Zljoni : acetone',

melhyl elh)'l ketone. dichloromethane, carbon dioxide, methanol, elhanol,

propan-2.()1 u hexane.

7581~

II ·prinCipji koloranti maduri n-ghamtiel Kidi taghhom hunu

)-( 10·Carbo ~ ylalO-4-ethyl- 1 .).5 .8.leuamethyl.\l-oJo-2-vinylphorbin· 7·

)'I)pn>pion.ale. copper complu (Copp'" chlorophyllin a)

"

).{ rO-CariIoA) r~yl-J-formyl_ 1 .s .8-lrlrnclh~r -9-0.o.2-vinylphorbin-

7-yr)prQpionalc , ~rconlpkx (Copper cliioroph)Uin b)

"',0.

Coppr:rchlorophyllin b (ghamll ai:idI): C" H. Cu

Coppn chloropllyllin I : 640.20

Coppr:r chloropltyUin b: 654.1 g

Ku U wll'ldl tiSIa' tiidicd hi I IJ da/tofts jrkk il-c)lc/op"litll),1 rillg jinfmoq.

Kontenut Ia' kJorofiliini tar_ram IOtali mh",. ;""al minn 9,5"w·umpjun

imnind r 100*C &haI1if:gha.

E :~m S6S fi ca40,5 nm fi phosphalc buffer ...... "'ju fi p11 7. S

E : ~ 14$ fi ca6JO nm fi phosphate buffer .wcju fi pH 7 , ,5

T rib afwJar , leur glial ikh:allsewdif:ni

Mauimu fi phospha~ buffer ...... "'ju fi pH 7. S fi ca40,5 nm u fi 630 nm

"""'"

U~

Methyl ethyl

Methanol

MhUJ; i tjrd minn SO mgl\& . wah«lhom jew

....,...,-«

"""'

"

rkombinazzjoni

Hu_

Mhu itjrd minn 10 mgIq

Mhux ii:jtd minn) nlgi\g

MhuA ii:jrd minn 10 m&lk&

MhuA iijed m;M I mll"Kg

MhuA it jed minn I mgfkg

Mhux iijed minn 200 mgfkg

Mhux ii:jed minn IJD1l> rniJl..;opper chtorophyUins 1()laI;

CI Food G~n 4.AMar Brillanci BS

l.-APIdar S jiHo nlilLi cSlenzjalmenL rlOdium N·\ 4-(di meLhy lamioo)

phenyl\2-h)WOA y.).6-di ... lf~ l. naphdWcny)mHhys.:n..J-2..k)'c1ohtudim-

l·ylidc ... [-N-meLhylmo:thanruninium II materja kolorami suuidjarja n;mk~n

l1'\li' klorur tas-iOdju uljtew .alf ... c. ... odju b/'Iala l·kom(:W'l$ti mhux iki<uluriti

prineip.li.

L.-Alidar S hu'll. deskriu bI'III I-melh tas-sodju . [I· melh cal-kaJCju II tal.

polJluju huw. "'koU permen ,

TriarylllWthal><

221-409-2

Sod iu m N- j·l-[ j4-(di methyl.mi no)phcnyll(2_h ydrol y-) ,6-disulf<>-l-

n aphlhaleny)- methylene [·2 .j·(y, l oheudin· l · ylidcne J-N-

melhylmcLhanaminium

Sodium j ·t ;I·d; lIIe thylamin<>-c:t-( 4-dimethyh minocyclohua· 2,!i.

dicnylide ... jbenzyll-6-hydro. y_7 · lu[(onato-n.plllh.lc .... 2-sulfonate (lKm

ltimiku "tenaHiv).

C"H .. N,NaO,5,

j76,/il

Kontenut mhu. i"'las minn 8O'9It tal·matrrja koloolnti toW; hlkulat bllaI.l-

melh w-sodju

1 720 fi ao 632 nm rsoluu:joni ak ... cja

E I"

"m

Tmb jtew granu" ikhal skur jtew aMar ~kur

MaSli mu n-ll ma fi CI 632 nm

!\.thu. iljtd minn 0.2 ..

Mhux iijed minn IJ)%

Mhux iijed minn 0,1 %

Mhu~ ii:jed minn 0_1%

Mhul iijed minn 02 ...

Mhult iijed minn SJ)%

Mhul i!jed minn 0.0 I % (kalkulati bflaJa aniline)

Mhu}. iijed minn 0,2% WIt ltoodiu:jonijiet newtnaJj

Mhux iijed minn 3 mglkg

Mhult iijed minn 10 mglk,

Mhu}. iijed minn I mglkg

Mhu~ iijed minn I mglkg

Mhu iijed minn 40 mglk,

II·Plain caramel jii; p~parlt bit_lrallamenl la' sban. kontrollata I.'

carbohydrates (Jwuleners nUlrillivi IU-lon. alimentari dis ponibbli

kummerejllmenlli hu~ l-"""''''''trs glU<;O$e U hucl<)S.e uljew ii-polymers

taghhom, e.g. ~iroppi tal-g)uoo5e. SUCI'OSe, uljew liroppi invenit;, u \kllJmt) ,

Gllall· promolljoni ial· k.ararneliuaujoni jislghU jimuiaw aeidi ,lJbili u melli,

bl-«teujoni la' ltomposti la'l-ammonium u sulphiieS,

l..ikwidi jew lOIidi kannella skur ghal su wed

Mhult it jed minn ~

OPI -0.12

Mhu~ Ii: jed minn 0.1'1.

Mhux iijed minn O~

Mllux itied minn I mg/kg

Mbu~ iijed minn 2 mgfkg

Mhu~ iije<J minn

I mgfkg

Mhux iijed minn I mglkg

Mhux iijed minn 25 nlgi\.g

lI.eaUSI;'; lulphi~ ""","",I tiii IRpanna bjl-tnlttamL'nI \a' ,rw... ko.urolJau

ta' carbohydrates (J "'urtllrrJ nulritti'" tax-xOl1a alimentari disponibbl

kum.......cjalmenll i huma I-monomers ,Iucose u fruceose u1jew il-potYIIlefl

u/it .... xiroppi invC'rtiti.udex~

~m . e ... xiroppi lal·glurosc. l ucrosc

b'xidi jew al kal i jew mingllajrhom. fil ·jmU nza .. • komposli IaHulphill

(sulphurou s acid. potauium sulphite. poW si um bisulpttil.e. sodium sulphik

u sodium bisulphile): ma jinluiaw ebda komposli la ' l-ammonium.

232-435-9

Likwidi jew solidi !<an .... !!a skur ghal ;.wcd

I.i:jed minn SO%

O.o!'i - 0.13

Mhu~ iijrd minn OJ %(')

Mhn iip! minn 0.2% (')

OJ-3j%(1')

ttP! minn 40%

19 - 34

Akbar minn SO

(I J !rin ....... ~ ,,,H.",, oi" 1Ior. ..... """'. !·as1OOl1'H"..." ,.' ..... ".I""i t." 0.1 ~ I'"'''' la- ,.,.. ... taI·t .l ..... 1.., ....... 1 n·ilma (,,,,,(I ,.

10m r~'~ ....

.. ro ........ to' J'I'O'lon b ';_,~ "' -k~l ...... '0,1 ____ ..... ,_

B ISO I

Mllul ;ijed minn I mJlks

Mh ux it jed miM 2 m&lk&

Mh ux iijed minn I m&1k3

Mh ux iijrd rniM 1 m&lk&

L-ammoni. can.mcl jigi ~paral bi l-ItalUUnenl la' shana konltOl1ala la'

earbollydn.les ("",eele"ul nutritliv; I.n-~ona ali_ntan di1pon;bbli

kum~rtj.lmenllj hurna. 1-",ollOmtTllluoose II frucrose uI~w ii-polymers

taJl!hom.e., . airoppi taI-r,luoose .I-UCIOIC. uljew a iroppi in-Uti . u dl:ltn»e)

b'Kidi jew IlI ka1 i jew mingllljrhom. m -pretcfl1..l ta' kompoa lao l-ammonium

(ammonium lIydroxide, ammonium carbonate. ammonium h)'d rosen

c arbonate u ammonium phosphate): majinluhw cbda. kompostllli· lo1fu .

232-435-9

l.ikwiw jew solidi Unnclla"-ur IItaI..,wnI

Mhua it jed minn ~

li:jed minn ~

O.oB - 0.36

Mllux iijed minn O;J'I. (')

Mllu~ it jed minn ~ fn&I\.& (')

Mhua iijed minn 10 mafkl (')

Mh ul iijed minn Ol% (')

0.1_ 3,3'1. (',

J) _ 3.5

Mhua itjcd minn I mJlk&

Mllua itjcd miM 2 m ..... &

Mhux itjcd mlM I mJlk&

'0.'.

.. ' """" .... ..

,.,.,1I· 1OIidi ............. ..,..",.. n-it_r.,.III.· 1<"'f610 ....

fl E.- r ... toaJ; etwl ..... Ia' k\d,. , ... k _ . rlt"""" Ia' """"'" ~·,1IItft>l11 ,oj . ~ ~hor la' 11.1 _"""'" M.i ..

M"u~ iip! minn I mglkg

Mh u ~ iijed min" 25 mgl\;g

ls-sulpMumrnoni. twamr'1;iii ~par;u. bit.lnlUllmellu , ' sl\ana konlro/Illt

ta' carbo"~drales (s ... ·uUllul nutriuiv; lU -.lorta alimenwi d ilponibbli

kummen:jalmenlli huma I·mon"", .. ,s glucOR' u fruclOSe uljr .... iI·polymel1

taghhom. e.g, xiroppi tal·glucose. sucro:Se .llljr w !l.iroppi invertit;. II del~)

b'aCidi jr .... alkali jr .... minghajrhom . fil·~unu taO komposti III' iulphi~ g

.mmanium iHMjn (sulph urous ac:id. pOlusium lulphite , potauium

bis .. lphi te, 5<)dium sulphite, loOdium bisulphil<', IIITlmonium hydrox ide,

ammonium carbonale, ammonium hydrogen carbonate, am monium

phosphate.ammonium sulphate. ammonium sulphile' U IIITlmonium hydrogtn

sulphile') .

232-435-9

Lik .... idi je .... solidi kannd\a skur je .... suwed

lijcd minn 5O'l>

0.10 - 0.60

Mhux ii:jed minn (J,6<l> I')

.\o1hllx itjcd m;nn 0 2 % I'I

Mhu. it jed m;nn 250 mg/kg (')

0.] _ 1,1'''' (' )

fJ,II- 2 .~'l> (' )

0,7 - 2,7

~ _ 14

Mhux 11_,. .... minn 'ill

Mhu~ ii.jW mmn 2 mw'~ g

Mhu. II.;. .... 1I1I"" I mw'kg

1",'''''_

(', L·;n1Cft,., '.1 ... 1 ...... , .. ~·Ii,," . ..... 1. 1_.,,,..,;",,,,,, ,.' "~,,,,, • .; .. ' 1I.I·j ' .. I. " ,,' .. ~.~ ,.10101", '01~·..- .. ,"-i II ,10, .. 1' .... ,', •. "' ...

" . 1»1 ... ,, _., "_ " ,. .. ,....,; ,. ' "" , ~ .. h'""",,,,u ,'" . ~ ... ,,' " ... "" ... _~ . ... ,

.......... -1 . ... N»I. 1 ....... " ... ~ 1"1'" , .... ,~." hi .. " . .. "., .. , ' ."" "." " T il , • • 1 , ., •

Mhlu iijed mlfln 1 milk ,

Mhux iijcd minn 2j mgl\g

CI Food Bl.Ick 1

I.-Iswro Brilianli BN ji ~l;on~i'li essoen~.hncnl flelraoodium ·4-,,«,lmmiJo..

5_hydrol y-61 7 ·sul ron.lo-4-{ 4-5ul fon.lophcnylllo)- I ·naphlhylazol

n1ph~cnc- I .7-disul fOl\.lIC U lI\It('fi- kolorlnll sunidj.r';' fli mkoen ma '

$Odium chloride uljew oodium ",Ifate brlal. I·komponcnti mhux ikkulurili

printiP-li .

1.·lswro Brillanli BN hu ..... de.!trill bh3111.mclh llHodju lI . mclh lal-kalcju

U uJ'~lju hu,,·. " 'koll permc ... ,

8imo

...

"

211).746-5

T elrllodi u m 4·acell mido·5· hydro . y-617 -sv I fo nalo- 4-( 4·su I fonal0 -

phenylazor l -naptlth ylazoJ narhlhlknc-I .7·dlluIf0N.le

86'.69

KonlCnul mhu. inq;as minn 8O'Jto 1,I·m,lefp kolOflWi lOIaIi hlkulal b/I:Ib 1-

mell'l t.s • .odJu

Mhu;l iijed minn 11.2'\11.

Mhu. it jed minn 10% (espre$$3 fuq il-kon~ nu( ta' koloranli)

Total mh ... i.l:jed minn 0,8%

Mh ... iip! minn 0,01% (bJkulati bl'lall aniline)

Mil ... iijed minn 0,2% larn kondizzjonijiet newlI"I.li

Mil"" iip! min,,) mgi\.

Mh ... iijod minn 10 mg/k&

Mil ... it jed minn I mgl1;:g

Mhu. iijed minn ] mglkg

Mh ... iJ:jed miM 40 mg/k&

II-karbonju VC'ietali jiii prodou hil-Wboniu.azzjoni ta' nwerjal vege~j

bhaI rna hum. "jam. ~sidwi 1aC«liulob, ~at u l-qJll1lW<OroIlut II qUT

oftra . II-materja prima liii karboniuata rt~mperBturi gholj • . Huw.

jikkonli$li ~iS('nzjalment rkarbonju linement divit . Ji5111' jkun lih ammont;

iglw III' niungenu, idrotenu u ossitenu . Xi ftillll' umdu jis.ta' jiii a»ofbit

fuq il-prodon wwa I·maniratlllfll.

71266

2 1j..6(1)-9

Kartlonju

c

lUI I

Ko.lIenul mhUl inqas minn 959l> III' karbonju kalkulat fuq bati anidla U

hiel u. mill-irmied

Tnb iswed. bla riha u bla IOghma

mooo-. bis- u tri5&lOj

A~o (tahlita ta ' kuluri

Tahlila La'

$Odium 4-(2 .<kIiaminophenylazo) bmunesulfonate

sodium 4-{4,b-diamino-m-rolylazo) bmu~sulfona~

disodium 4,4' ~4 ,6-diaminc). [.l·phenylerll.'bi~)di (benzenesulfonate)

III

disodium 4 ,4 ' -(2.4-diamino-l J·phenylenebis.azoJdi ~~ ... If<mille)

IV

V d i Jodi u m " ,4 ·.{2 ,4- di amino _ 5· meth)' I. ] .3.ph~nylenebi5azo jdi

(benuJ1elulfooate)

4,4 ' ,4 .• -( 2 ,4-di am i nobc n7.C ne- I ,3 .~ -(risno II.;.

V I

Hi sodiu m

(benl:(: nesl! I f onate)

I C, )H" N,NaO,S

II C" H"N,N.o,S

III C"H"N. NI,O.S,

'V C"H" N,Na,o.S,

V C,.H .. N. Na,O.S,

V, C,.ll,..N,Na,O.s.

,

31 4 .30

328.33

II

520,46

III

'V 520.46

V 534 .47

V, 126,.'l9

KomenUl mhu1 inqas minn 70% taI-nulefja kolonnli tocali

Mill-materja kolarlnli lou-Ii prrienti l-pl"OpOnjonijicl tll· ko mponenti

m' gtlandhomx jeCCedu

20%

17%

I[

III

17%

IV

16%

V

20%

VI

16%

Mh ~ . i~j<.-u minn Ul%

Mhllx iljed min" l Y,o!.

Mhox iijed minn 0,7%

Mh" x ii:jed minn 0.15%

Mho. it.jed milm 0,007% (kalkolati bhala aniline)

Minn soluzljoni la' pH7, mh". ii';"'d minn 02%

Mhu. iijed minn 3 mglkg

Mhu . it jed minn 10 mg/'Kg

Mhu. iijed minn I mglkg

Mhu. iijed minn I mg/kg

Mho. iijed minn 40 mglkg

C[ Food Brown 3

II-K annella I IT ji H:on,i,[i essenljalmenl fdi>O<iium 4.4"_( 2.4--dihydro. )'-5-

hydroxymelhyl - I .3-phenylen c bisazo ) di (naphthalene· I·su Ifonate) u

fmaterja koloranti sus,i djara n imkien rna' klorur ta,-sodju " I jew solfat bhala

lJ·kompooenti mhu . ikk ulurili principali ,

tI· Kanr..,lJa HT huwa dc,l riu bhala I-mdh [a,-,odju . lJ·mdh tu ll· kukj u u

WI'potIS' jU huwa wkollpermess.

Hi ... ",

Di,oJlUm 4.4 '.(': A-<lih)'Jrox y-5-h)'dro\ )nwlhyl - I .I-phcn)"1cn< hi sllO) Ji

(naphthalcne - I -,ul fonatc)

K,,"tc""t IIIh"x in'l'" mi" " 70-;" tal · m"tcrj.1 knloranti tOiali lalkolat bhala 1·

nw lh t:". ,,~ljLl _

E 1% .jO,lf,.·a4Wnll1 1\"lul.ljol1iakw<j"npH 7

kn '

Trab jew sranuli kannetl. - hamrani

Massimu fl -i lma ta' pH 7 fi ca 460 nm

Mhu x iip:! minn 0,2%

MhuK tiP:! minn 10% (TLCmelhod)

Mhu.. tiP:! miM 0.7%

Mhux it jed minn 0.0 I 'It (bIkullli bfIaIa aniline)

Mhux tijed minn 0.2'lt rsoluzzjoni taO pH 7

Mhux iijed minn 3 mgllcg

Mhult Up:! minn 10 mJl1<g

Mhult tiP:! minn I m&flcg

Mhux it jed minn 1 mgllcg

Mhux it jed minn 40 m&flcg

CI Food Oran~ ~

1I·<arotcnes imltalJta jinki.\bu bI~SItaZ2joni b '$Olventi ta· teneri nlwrali ~'

pjanti Ii jilljek]u. karrolli, ijut vegetali, "'Mix, alfalfa (1u~m) u hurrieq.

lI-prinCipju kolon.nti prinCipali jilckonsisti rClrolenoids Ii I-pam ].k.birI

minnl>om tkun iffurmata mi!l·~ta.;,:aroICroe . a ·,y.;,:arotene u pi~nti olin

jistg"'u ileunu p~ienti . Barra mi ll-pigmcnti taI·kulur. din ;$-SUSIanU jiSla'

jkun fiha ijul. xaPlmijiet II lama' nalUrali tal-materjal ta · origin;'

Dawn iHOiventi Ii tewn biss jiUJllu jinlUiaw n~strazzjoni : 1CeIOnC. methyl

~lhyl ketone, methanol, ethanol, propan·l-ol, hUane, di~hlQR)me!hane ~

~arbon dioxide .

15 130

Konll:nul bfIala~1 (kalkullti bfIalalkarotene) mljkuru inqu minn

.'i*.GI'IIJ prodoIIi mibubin bI-nuaujoni tI"ljut""FIIli: mlwA InqIIS mioo

O,N. rAahmijitt Ii jillkklu

E 1'10

2SOOficl 440 - 437nmincydohUIIlIe

1=

M llsimu fi cycloheune fi 440 - 451 nm u 470 nm - 486 nm

A_

Melhlelh~l ketone

. """"

Mhu1 itjrd minn so m&fkl. wIhedhom jew

M""""

_'<>I

rkombinaujoni

,-

Dichloromctlwoe

mhUl iljed minn 10 maJk,

Mhul itied miDn 3 mJllr;:I

Mhu1 iljed minn 10 m&fkI

Mhul it jed minn I m&fks

CI Food Orange j

O:."-n I"sp«,fibujonijkt pppl ikaw b'mod predomin3nl, ghal kull u:ms

isomer iH:a""~,1C flim~; .. n ma ' an,nl!)n!; igh~r In' carotenoid! oI'Ira. Preparnl i

d,]",i!, u Sl2btHlil..:Il' .iis"" j kun lihom ci .... lnIIs isomer r:alios differenli ,

Carotenoid

."00

536.88

Mh ux inqas minn96% t:l1-mal~rja ~olOfanli lOlaIi {espreil bhah Jkarotenc:)

2 SOO Ii ca 453 _ 456 nm Ii c)'c1ohe.\ ane

E 1%

"m

Trnb kris(al1in je .... kristall ~ ulur ahmar ghal kannc:Ua - tlamrani

Mani mu Ii cyclc,lIuanr Ii "'" 453 ~ 456 nm

Mhu s it jed minn 0 ,2%

CarotinoKk minbatr.l ~",n.rot.".lC : mh. itj<d minn J,O% tal -materja koloranli

",",;

Mhux iijed minn 10 ms/ltg

Mhux iijed minn J mglkg

Mhus iijed minn I n,glkg

Mhu, iijed minn.w m"kg

B 15 11

Carotenoid

1.5 120

Annatto: 215-735-4 , eSl.ratt tai.·ierriegh~ Ia' -ann:uto: 2g'1-S61-2: biain: 230-

248-7

Biai n: 6' -Methylhydrogen-9-<;.-6.6 -..oJiapocarolcne-6.6· -dioale

6 . _ Meth ylhydmgen _ '1 - .t ran~-6 ,6 --di apocarQIe .... -6.6 -..oJ;";'I<"

NortI;xin, 9'(i,_6.6· ..oJiaJlOCarou.ne-6.6· -diQie lI(id

9'-Trans-6.6' ..oJi3J1OCarolene-6.6' -dioie acid

Biain

ClI H .. O,

C" II,.O,

Norbiain

Biain

394 j I

Norbiain: 380.48

Trab. suspension je .... solul..ljonlll· kulur h.:tmr. .. " .kannella

Bi ain: massimu Ii ehlomfonn Ii Q S02 nm

Norbi xin : massima rsolulljol1l KOH d,I"'ilD fj ca 482 nm

(i)

II-bixin jig; l""C'p.tr.lt bl-rstraajon' tal-n"'ti~.~ Ill ' flKj barra w: -tr;"tagh laS-

sigra II' I_annatto 18j t·" o,-dlmlU L) b' soI~ent;'-w ,i:jtd minn tb,,-n Ii gejjin

acetone . methanol. ~.a"" .ie'" dtch\oronlelh""" . eamon dioxide kg,,·;t bit-

IMhllij.;o las-solvent .

In· nortIixin jiji prrparal b - hyJml.'-Jil b ' albJi :ok .. ~ji !al-biain eStral!.

II-bi xin u n·not"bi . in jista' j kun fihorn mal<"rj:lI ichor "'tr:>11 ntii;-lem..-gha

ta·I _;llln:1no.

II-tf .. h l:>H.i.;n lih di"~rsi Lumpon~mi ~ uluri ti .l; dal pri ..cip~1i hu .....

l· h;IUl.1i ji.l/!hu ,Lunu pre1.em i ken,n, n ./!h3ml:l ,i. - kif u~ oll n·Shml.

Im" .. -. J iS l~h\' ikllnll " 'koll pr" , ~nti proJuu i taO dcjI. .... daz zjoni lermita

taO hi , ;n .

It_t r~h IlliH, .. rbt~tn fih il· p;u..l..tl llal·h)·un>I)·<i; tal-bi. in . fl-gi'lamla la ' "",Ih

I,,<-... >djll';"'" "' .... ,,,:ju ""'"a I-I'"no."pju kuk>r.mli prino.'ipali . Ji $lghll ikunu

pr";"nli l-;.l>WjI. ~ba",li.'1 ,-i,· u Ir:",,- .

",,,!Ill'nUl I'" Imll ~,' t>i.in mhu. i,"I'" ",inn 7.~'k la' ,",lrQl~noids to ta!i

t:.ILul;o't hb~b I>ui,,_

", .. "".,,,,, la ' lr:,h 1,,. ""rbi.in mhu . illlla. minn 25% taO caroIenoids IOtaIi

~"I k lliati hbab ,~ ~·hi , i"

, ,. I,m

2870 f, ca S02 nm Ii chloroform

Bixin

,

I~

2870 Ii ca 482 nm rsoluujoni KOH

NOI'bixin

10m

mhux iijed mi"" 50 mglk" w:Wdhorn jew fkombinazzjoni

)

mhux iijed minn 10 mgi'k,

Dichloromcthane

MhuA iijed minn 3 mglkg

Mhux iijed minn 10 mglkg

Mhux it jed minn I m8fks

Mhux iijed minn I m&fk:g

Mhux it jed minn 40 mglkg

(ii)

AnnatlO 50Iubbii fl-ilma jig; ~pamt bksuuzjoni b ' alkali akweji (idronidu

tas-sodju jew idrossidu tal-pocaS5ju) tal-roaril.g ta' fuq barn tai-lrietagh

w-sigra 1&' I-annatto ( Bua OI'tlianD l-)

L-annallO IOlubbli fl-,I ma fih in-norbixin. il-prOOotl ta' hydrolysis tal·bixin.

n-,lIamll u· _Ih ~-sodju jew lal-potanju. bI\ala I.prineipju koloranli

prinCipali. L-ghllmliel cis- u U1Ul.- jiSlghu ikunu preiemi .

!kun flh mhU l inqas minn 0.1 % 1a1..:arorenoids tolal; espreu bhala norbixin

1%

2870 Ii '" 482 nm rsoluujoni KOH

Norbi.in

E

1=

Mhux ii jed minn 3 mgl\g

Mhux iijed minn 10 mgl\.g

Mhux iijrd minn 1 mgl\.,

Mhux iijed minn 1 mglkg

Mh ux iijed minn 40 mglkg

(iii)

ESl/lIu; ta' ,_annattO fii-tejl. bhaJa sol uz.:r.jon' jew SI<S/1<'nsioll. jign prepatati

bI-estrllZZjoni IIII-<'fl(llillg Ill' f"'l b.ura tai-i:rieragll laS-sigra \a' I·annauo (8i.w

o rtl/Dlt D L.) b'tejt vegelali Ii jiniekcl. L~S!",u ta' I·annalto fih diversi

komponenti kuluriti, Ii dak prineipali huwI l-bilin, li jislghu ikunu p<denti

rkemm '_gtwnlacis· kifukoll n-ghamla trnns_ , Jistghujkunu wkoll prei:enti

prodotti ta' deJflldazzjoni tennika ta' bixin ,

Ikon fih mOOI inqti minn 0,1% taJ-arocenoids esprn. btlaIa bilin

E I 'll

"m 2870 fi CllS02nm fi chloroform

Mhul iijed minn 10 mgfk.g

Mhux iijed minn I mglkg

Mhu. it jed m;nn I mglkg

Mhu. ii:jed minn 40 mglkg

Paprika O~sin

~ SI/llU tal-paprika jinkisoeb bl-esuuzjoni b' solventi ta' Seneri naturali ta'

paprikA, Ii tildonsiui f1-imiicwed mithuna tal ·frotl, bi jew minahajr Ii·

imiegha tal-Copsirum OMltUm L .. u fiha I-prineip; i ko lonnli prineipal; ta'

<bn l-iJpiu. Il -prineipji koloranti prineipali hurna l-capsalhin It l-capsorubin ,

Hija maghrofa I·~unza taO varjeti tbin ta' komposti ku luriti o/Ira ,

ea"'n is·solventi Ii genin biss jistghu jintuilw f1-Htta.U.joni: methaool .

etharol. autone, ""lane. dichloromo:thanc , ethyl ~1.I1e u ClIIi:Ion dioxide ,

CaroIeOOid

Capsanthin

207-364--I,capsorubin: 207-42S·2

Cap,amhin: (J R. YS, YR)-3,3 - -dihydroly·~"k-Carotene-6-one

Capsorubin: (3S, 3 'S, 5R SR '}-3Y -dihydtoxy·k"k-carotene-6,6 '-diane

CaJlWllhin: C.,H,.O)

Capsorubin

C.,H,.O,

Cap.",,,hin; 584,55

Capsonobin ' 600,115

Eslratlllll -POIIlfi ka ' kOllienU! mhu~ ;'''Ias lIl;nn 7.0% carolenoids

Cap."mh'nfupsorubtn: mh'" ''''Ia, minn JO% Ial -carolenoids lOCali

2 100 Ii Q 462 nm fi acetonl'

Jii; proOOIl k ... ·n ikhal Jkur biHonitI Ia' qalra andu j.Ulfonku ma' qaqa taI-

Um!,jlan r 2 - j '1;11';"\ t hlorofo.-m

Ethyl ""'""Ie

Methanol

Mh"x iljtd monn 50 mJl\& .... ~hom,itw

"""'"

rlO\nb",aujoni

Henne

Oichlororncl h;1l'l('

mllu. 'l,itd milln 10 mgfk.g

MIIUl ,I;jrd miM 250 mglk.&

M il", Iljrd minn j mJ14

Mhu Iljrd minn 10 ml'kr

Mil", 'ijed minn I mp\:~

Natural Y<'Ilow 27

II.,)·CQJI""" "nbwl! bI"',IUUjlnO b· ...... ·~Il" !:d· ... ·""ri _"",Ii la' l:o.iom

I..,

llImar I L., ... "...r .• ".,,,, t"·~IMI~'"

btl-1""hhop ,."..."w~n" w._loQIwent

OiI...-n .. ·0;01""nu I, i<'.lI'n lit .. ,,'-I,.,u Jomuuw d,,·h~. c;orl!on

dKIIidt'. ethyl ar.;CI;W~ . ....... \01"'. JlfUl"'Il-2 ... I. mt;11wtoi . cl h,mol. lit u "". II·

B 15 15

prinCipju koloronll priocipali u(.IlOdam huw~ 1)'COlX'"", ammonti I:ghu u'

pigment; ClII'OWlOid j;,IgJ\u ikunu I'rdcnti . 8arra mill-pigmenti ta' kulur I-

ohra j·proOOu jista ' jkun fih tjllt. uhmiji\'l , uma' , u kompor!C'nli naturali

la' IOghma fit-udam .

Carotenoid

75 125

Kon~nul mhUl inqa. mi"n 5% taI .materja koloranti 10la1;

E 191. )450fi0.472nmfi~une

I <m

Likwidu viskuz ahmar ~k ur

MlISslmu fi ~x""" fi 0. 472 nm

Ethyl a.cet3te

,-

Methanol

Mh ul iijed minn SO mS/ kil. w~h~<Jhom jew

r~omhi~joni

A<.'O"IO""

lIu:IIIe

rrop.. .... 11l1

Di c h IOr"IIldhanc

Mlmx i z~<J minn U.14

Mhux i7.;'-..I minn.1 m~tt

Mhux iijnl minn 10 mjll"l:,.

Mhux iiFtI mi"n I ,nj!.lkg

Mlnu ii;'''' mi"n I m!V~ g

CI Food Orange 6

Dawn I.i,pe<:ifiuujonijiet japplik.w b 'mod ~dominanti glial kull Ira",

isoml'T ta' p..~8 ·-<arotrnaJ flimkicn rna' ammonti tgtlar LI' caroknoids

o hn . G flaml iei dilwiti u stabilizuti jigu prepanti minn p..ap0-8' -<,mien&]

Ii jissociisf. dawn "i s~cifikaujonijiet u jinkludu wl uujon ijiet jew

susptns;ons ta' l'-apo·8' carolenal ruh mij iel jew ijut Ii j inieklu,

emulljonij~1 U lfl1b dispn$ibili bl·jhNL o..wn il'Pf"panti p ILI' j.kun fihom

cislt""'i isome , ratio» differenti.

Carotenoid

<0820

214-17 1·6

p..Apo-S' -clll"Qtenal. Tran.-p..apo-S ' carotene-aldehyde

41 6.6S

Mhux inql$ minn 96% tal·male'ji koloranti kollha

2640 fi ca 460 - 4<i2 nm in cyck>he~anc

E 1%

I,m

KrisLll1i vjol. sku. b 'leqqa IJl<'talliki je..- trab krisu.lli n

Massimll fi cyd o hcxane fi 460 - 462 nm

Mhu~ i.l:jed minn 0,1%

Carotenoids minbarta p..apo-S ' -carotenal

mhux iijed minn ]J)% bll·malerj; koloranl; 100 lii

Mhux ii jed minn] mgfks

Mhllx it jed minn 10 mgfkg

Mhux iijed minn I mg/kA

Mhux it jed minn 1 mg/kj

Mh ux iijed minn 10 mg/kg

B 15 !?

Cl Food Orange 7, ~-ape-8' -carotenoic este r

Dawn l_ispeeifi kazzjon ijietjapplikaw b'mod predominanu g~aJ kn llirnns

isomer la ' ~-apo-8' ...;W'Otero:;>ic acid ethyl ester flimkie n ma' ammonti i8~ar

ta' car<)lero:;>i<k ohra. G hamli~t dilwiti u stabiliz2.ali jigu preparati minn~­

ape-8' -caroteooic acid ethyl ester Ii jissodisfa dawn l-ispe.:i f,kazzjonijiet u

jinkludu S<lluujonijiet jew suspensions la' ~apo-8' ...;aroteooic acid ethyl

eSter f xal'tmijiet jew ljul, emnl sjonijiet u trab dispersibil i fl -ilma, Dawn il-

preparati jista' j knn fihom cis/trans isomer rali~ diff~ren!i .

Carotenoid

4()825

214-173-7

~Ape-8' ...;aroteooic acid e thyl ester, ethyl 8' ,apo-~...;arotene-8' -nate

C"H .. O,

460,70

Mhu x inqas minn 96% taJ-materji koloranti totali

',m 2550 fi ca 449 nm Ii cyc101lexane

E 1%

Kristalli jew trab m Slalli n la' lewn ahmar ghal vjola-ahmar

Massimu fi cyc10hexane Ii ca 449 nm

Mhnx iijed minnO,I%

Carotenoids minbalnl ~-apo-8' ...;arotenoic acid ethyl ester: mhux iijed minn

3.0% tal -materji koloranti lotali

Mhux iijed minn 3 mgfkg

Mhux iijed minn 10 mglkg

Mhux iijed minn I mg/kg

Mhux iijed minn 1 mgfkg

Mhux iijed minn 40 mglkg

Carolenoids mllallta , Xanlhophyll.

II-Lutein jinkisoeb bI-estrazzjoni b'5Olveoli tal'imer! nalurali ta' frou u pjwi

Ii jittid;lu, lllui~, l..tern (alfalfa) u '''Sms ~'«fQ.. U·printipju koIoranti

printipal i ji kkoosi sli r caro<enoids Ii minnhom il·lutein u l-eslers II ' aCidu

ul'lmi jiffumlaw iI_part; prinCipali , lkunu wkoll prdenli ","monIi vlIljabbl;

\a' caro<enes. 1I·lutein ji$l.1.' jlr::un fih ~atunijiet, tjlll U laml ' o&tunli tal-

pjanta.

Dawn il-wlvenl; Ii gejjin bi n jislghu jinluiaw gl'lall -estraujoni : metlJanoI ,

ethanol , ~·2-o1. henne. acetone, methyl ethyl ketone ,dicl'llorornethanc

u carbon dio~ide

Carotenoid

33' -d.ihydroxy-d-caroo:ne

"U8

KonlCnut tal ·malerja. koloranli lCU\i mbu~ inqQ minn 4% kalkuLat bIIala

lutein

L~

,

2 j5Q Ii a. 44S nm Ii dlJoroforJWetl\ (10 + 90) jew Ii

L, m heuneletlJanoUlICelOne (80 + 10 + 10)

L.iltwidu sltur. ufrani kannel la

Massimu Ii chloroform/ethanol (1 0 + 90) Ii ca 44S nm

A~

Methyl ethyl kelOne

,....

M .....

Mh u iijed minn 50 mg/kg. wahedhom jew

rltombinazzjoni

Propan-2-c1

He~ane

mhll~ it jed minn 10 mgl1tg

DichlotOloxthane

Mhu ~ iiFd minn 3 mgllr::g

MIIuI iijed minn 10 mglq

B 15 19

Mllu~ iijed minn I msfkg

Mhu~ iijed minn I msfkg

Mhu~ iijed minn 40 mglkg

CI Food Orange 8

Dawn I-isp«if,kw:jonij~t jappli kaw b'mod predominant; ghal kulitrall5

isomer la' """thaunthln tlimk~n ma ' ammonl; tghar la' carotenoid$ nllrl.

L-ghamliel dilwiti u stabiliWiti jigu preparali minn ".mluuanthin Ii jissodisf.

dawn I-ispe(:ifikw:jonij~l u jinkludu soluujonijiet jew SII"fH" SiOflS ta'

cantt.a,.aothin ruhmijic.t jew ijulli jitt~klu . tmuisjonijiet u IBb dispersibili

H-ilm • . Dawn il-p~rati jim' ]kun lihom cislUwl, isomer ratiosdiffm:nli ,

"'.so

208-187-2

~Carotene-4,4 • .diane. canthaxanthin. 4,4 ' -diolG-lH:arotene

"m 2 200 Ii fl ". 468 485 _ 472

run fl chloroform

E 1%

nm Ii

cyclo~une

Ii 464 - 467 nm Ii petroleum ether

KristaJli jew trab kristali in ~joll w.;ur

Mas!oimu Ii "hlorofonn Ii (1 48 5 run

M ... ,imu Ii cy"lohe~&ne Ii 468 -472 nm

Massimu fi petroleum ether Ii 464 - 467 run

Mhu x iijed minnO.I %

Carotenoids minbarn cantllaunlh in : mhu~ iijed minn 5.0% tal-matetji

kolononti IOllIli

Mhu iijed monn 3 mglkg

Mhu~ iijed minn 10 mglkg

Mha~ iijed miM I mglk,

Mhu~ iijed minn I mg/k.g

m&Iki

Mhu~ izjed minn 40

AIIIlIaI' Pilfavi

L-Allmar Pitnlvi jinkiSl:b min .. j<:neri nawf1lii ~' piUllvi aflnlllr (&IlI vwl}/Qr/s

L. VII" , rubra) bl-allasir tl' pilfav i misll"'l bhall 111,11 taHghasir je ..

b'O:Stnupni ak_ja ~' pilravi mqana' lI.nkjammt lUne,-i fil-pri~pjI

attiv, lI-kIIlllr hllw. kompost minn piamenti diITermti Ii hllma kol]'" 111_

kl,"si betalaine , l1_prinCipju kolonrMi prinCipaii jikkon$l$li rbdac:yaniM

(homer) Ii minnhom il _bet ... in j iffonn:a n - 9.5%, Ammonti zlIl'IIr ~'

betaunthin (isfar) II prodoui ~' degradaujoni ~' bewainel (~1I1 c.)

jiJt&flll ikunu I'rdrnti ,

Bam. mill-pigment; taJ-kulur ii-lUlU jew eSlratt jikkoolisli rzoKkor, mel~,

uljew prettin; naturali lII _pitralii ahmar,ls_lOluzzjoni tiSl.l' liii IdonCenIrall

iitu

raffuwi sabir~ titnl:hllll_biCta I.eM ~

• uhud mill-proOOIti ji$lllhll

zokJu:,.., _III u proteini ,

2)1-628-.5

(S , (K' ,R -)- 4 -(2-(2-Clrbo~y-,(p·D-g lucopyranosyloly)-2.3-dihydro-6-

hydro.y-' H -indol· l -yl~thenyt~2J-dihydro-2,6.pyrid.ine-dH:atbo~yli<: Kid;

1-{2-(2Jt.dicartool y-l :! J ,4-!.elrah ydro-4-pyrid)'1 idene ~Ihyl idene)- .5iH),

atucop),ranoJylru y )-t>-hyoJrol)'1 ndoli u ro-2 -<=II'OO~ ylau

KOnt.:nul la' kulur allma! (esprus Ii belanine) mllu~ inqas minn 0,4%

I "m .

E

1120licaS3Snmrtoluzzjonillk_jalipiI S

Likwidu, pasta,lfab jew soIidu ta' k""n . I'linar jew aflmilr l kllr

M.uimll n . ilma u ' pH 5 Ii c. S)S nm

8 152 1

Mhux iijed minn 3 m&l1tg

Mhux iljed minn 10 mglkg

Mhul i:ljed minn 1 mglkg

Mhux izjed minn 1 mglkg

Mhull izjed minn 40 mglkg

L-anlhocyanin. jinki$t>u b't$traujoni b'i lma bi s,wlphite, ilm. aeidif'kat.

tarbon dioxide. methanol jew ttltaDol mill·g.:neri naturali La' lu.t.ijell u frott

Ii jiniekcl . L-atlthocyanins fihom kompooenti komunj wl·rrwerjal \a ' origini.

jijifleTi anthocyanine, K-idi orpnici, Wlni"" ;roI;kor , minerali ei:i:. iida mhux

ne.'en arjament H.j",," propmjonijiet kif jinsabu fiI·matery,1 \a' orijini .

Anthocyanin

208-4 38·6 (cya nidin): 205·125·6 (peon idin ): 208· 4]7·0 (delphinidin)

2 11. 4(l3·8 (ma/vidin): 205·127·1 (pelargonidin)

.s

3.3" ,4 ' .1·~tahydroly·n.vyl ium chloride (cyanidin)

3.4' .s.1· T etraItydroly-3 ' ·""'tOOxyn .vylium chloride (peonidin)

J.4 ' .5.1· T etraItydroly·3 · ,S" .(jimctholyflavylium chloride (malvidin)

3.5 ,7. Tri hydrol y·2·{),4..'i. trihydrolyphenyl}- I.bon~opyrylium chlori<J<.

(<J<.lphinidin)

3.3'4' j .1·Pe ntahydrox y·5· ·metholynavylium chklri<J<. (petunidi n)

3 .S. 7. Tri hydro l y. 2·( 4 · h ydrOl ypheny I )·1· ~nlOpy rHi u m ch loride

(pelargonidi n)

C)'anidin

C"H"O.Cl

Peonidin

C,.H"O.C l

Mal vidin

C"H"O,Cl

Oelphinidin

C"H "O,C I

Petunidin

C,.II "O,C I

Pelargonidin

C" H"O,CI

l22.b

Cyanidin

Pe-onidin

336,7

366.7

Malvidin

340.b

Delphinidin

352.7

Petunidm

306.7

Pelargon,din

,,.

300 ghall· pigmen' por fi 515·535 nm Ii pH 3.0

E 1%

ldenlifikuzjoni

Massimu fi metllanol fi 0,Dl% com:. ~ICl

Cyanidin

S35nm

Pronidin

S32nm

Malvidin

S42nm

"',m

Delphinidin

PelUnidin

543 nrn

SlO nm

Pelargonidin

Puri~

Residwi Ia' solventi

Methanol )

Mhu~ iijed minn.50 m&fkg. wahedhomjew fl::ombinazzjoni

Ethanol

Mhux uj::d minn I OOO.g ~r ~nt pigmenl

Sulfur dioxide

Mhux lij::d minn 3 mg/l[a

Amniku

Mhux it jed minn \0 mg/'k&

Comb

Merkurju

Mhul itj::d minn ] mg/l[a

Ktldmju

Mhul iijed minn I myq

Metalli lqal (btud Pb)

MhUI iij::d minn 40 mg/ka

KARBONATTAL-KALOU

C[ Pit,meD1 Wh.ite ]8. Chalk

Sinonimi

II-brbonat taI-UICju hoWl I-prodon miksub minn Zonqor milllun jew bil·

Defi nizzjoni

pretipiw.zjoni Ill' cakium ions ma' carbonate ions .

Klassi

lnorganiku

Nunuu taI-lndici lal-kulur.

77220

Einecs

KarlK:>nat taI-b.lcju: 207-439·9

Zonqor.

2 15-279-6

Karl:JonaI w-b..Ieju

caC0 J

Formula klmila

100.]

Pit molckulari

Kon tenul mhU1 inqas minn 9S% fuq il-baii anid",

Tnb krit tallin je'" bla forma abjad, bt. rir.a u bla togI'Ima

Prnuika~nt insolubili II-ilma U n·aJkohol. JinhaJl b'cffcrveuenZi f.cidu

&«tiku dil",it , f"" idu idrokloriku djJ",il U f'aeidu nilfib d il", il . u s-

soluzzjonijiet riiultanti. "'Ma t-lOghlija, jaSh!u provi poii lli ~i Sllal kalcju.

Mllul iijed minn 2,0% (200 °C, 4 IIoUB)

Mhu1 iijed minn 0.2 %

'*'

I\.1bUA ii,iro minn 1..5

Mhu~ it,iro minn 50 m&fk&

Mhu i.i:,iro minn 100 111""" ",ohnIhom jew fkombinaujoni

Mbul iijed minn) mg/kg

Mhux iijed minn 10 m&fk&

Mhul il:jed minn I mgikg

CI Pigmenl White 6

Id-.dijo .. idu t.al.tilllnj u ji kkonsiSii usc nzjalment fanata5C titanium dioxicle

pur Ii jist.a· jigi coorw b ' ammonti zSh ... ta' alumina ulje'" 1ilica biex jillejbu

l-k"'aJiu.jiet teknologiCi ta!.proOOu.

InDfpniku

77S91

236-675-5

Dijosiidu IlIt_titanju

TiO,

79$8

Konll:nUI mllu~ i"'las minn 99'if, fuq ~ Ill' bla alumina u silica

Trababjad bla forma

Ma jinllall. n·ilma u rsolvcnli organic;. Jinhll bil·flil il·flil r.cidu

flooridriku u r.Cidu solforiku koneenlr:ujahraq .

Mhu.l it jed minn OJ'lt (10' -C, 3 siegllal)

Mhu. it,ied minn l.o'lt fuq baii Ill· bta mRlI:1'ja volatili (800 ·C)

TouJ mhull. iijed minn 2.o'lt

MIlu! iijed minn 0,S'lt fuq ~ Ill· bta alumina u sil ica u, ghall-prOOOllj Ii

jkun fihom I·alumina u ._silica, mhu. It,itd minn I's'lt fuq ii-bail tai-prodoll

kif mibjug/l.

Mhu1 it jed minn O,S""

MbU.l it jed minn I ml!lkg

Mhu. ii,ied minn SO mglk, billi jinh.all ghal 1:;01101

Mhu~ ii,ied minn 3 mglkg billi jinh.aJ1 gh.al 1:;01101

MhD1 lijed minn 10 ml!lkg billi jinhall ,hal kollo~

Mhu it jed minn I mglkg billi jinhall ghal 1:;0110.11.

Mhu. itjrd minn SO ml!lkg billi jinhall g/IaI koIlo~

Iron O~Kk YelloW: CI Pigmall Yellow -12 and 4)

Iron Oxide Red

CI Pigment Red 101 and 102

Iron Oxide Black

CI PiglnCnl Black 11

L...,.sidi I.al·hadid u I-idrossidi IllI·hadid jigu prodolti b·mod sintetih II

jikkonsistu esse nzjalmem rossidi taI-hadid anidri uljew idrati . L-istala iii·

kuluri linkludi isfar. atlmar. kannelll II iswed. l.-ossidi I.al-lladid taJ(-A[lIU

t.' I-ikel jintghufu primarjamcnt mill-grldi tcknici bit-livelli

kompanmivament bani taO kontaminaz.zjoni b'me talli o hra. Dan i, ir bl-

ghaila u l-ko nlrOll ta~-sors lal -hadid ulje ... bi I-grad Ia ' purifikaujoni kimi ka

matul H -pro¢~S$ tBI-mani(allurn .

lnorganiku

Iron O~ide Y~lIow : 11492

Iron Olide Red

11491

Iron O~ ide Blao::lr.: 77499

[ron Oxide Yellow: 257..Q98-5

21~·168-2

[ron Oxide Red

[ron Oxide Blao::k: 235-442-5

Iron Oxide Yellow: hydrated ferric oxide , hydraled iron (11 1) olido

Iron Oxide Red : anhydrou s fmic o lido, anhydrous iron ( II I) oxide

Iron Oxide Blao::k: fenoso felTic Olide, iron ( lJ, Ill ) oxide

Iron Oxide Yellow

FeO(OH).d-l,o

Fe,O,

Iron Oxide Red

[ron O~ide Blao::k

FeO.Fe ,O,

88,85

feO(OU)

159,10

Fe,o,

231,55

FeO,Fe,o,

bfa.r mhux inqas minn 6Q'I. , ahmar u iswed mhu. inqas min" 68%tal·hadid

toeali.npren bl'lala hadid

Tnob: ta ' leWD isfar , ahmlr , kannclJa jew i.wed

InSQlubbli fl-ilma u r solventi organici

Solubbli f'xidi minerali ko nttntrali

Mhul iijed minn 1.0%

Mhul iijed minn 3 m&lkg

Mhlll iijed minn.so m&lkg

Mhux it jed minn ~ m&lkg

Mhux iijed minn 100 m&lkg

Billi jinhall &hal kollox

Mhul it jed minn .so msfkg

Mhul ii:jed minn 20 m&lkg

Mhul it jed minn 1 m&lkg

Mhu. it jed minn 200 mglkg

Mhu . i.ljed mi.m 100 nlg/kg

Cll>igmen l Melal , AI

IHl3b la' I·aluminju huwa komposl minn paruttll i fini la'l-aluminju . h·

Ihin ji~UI' jsir u jisla' rnajsi~ r,l'prdenza ta' tiul ve~lali II jiuirkl u uf}t'"

':idi xahm in tal·k walitl!la' addilivi la' I·ikel. Huwa hieles minn talIlil

b'sus!anzi ohra minbana tjul vegela li Ii jinicklu uljew atidi ~ahmin tal·

kwalitl!la' addi livi la' I. ike! .

'"''''

23 1-072·)

Alumi nju

Al

26,98

Mhu ~ inqRS minn 99'lo kalkulati bh.ala AI fuq bat, UI' bla ie)

Trab je w foljl t krjknin ku lu. grii: r,l·fidda

Insolubbli O·ilma u rsoh'rnli organiCI. linhall rai:idu idtokloriku dil wil. b·

soIuujoni riiultanu UI~li provi poiiluvi JIIaI alumln';".

Mhu~ it,iW minn 0.5'1> (IO~ *C, $I pit kostanti )

M hu~ it,iW minn) mg/kg

Mhux iijrd minn 10 mgIkJ

Mhu ~ it,iW minn

I mgi'kl

Mhu~ ii,iW minn I mgi'kl

Mhu x it jed min" 40 m&J\i

A,&<,nlum. AI

1norlaniku

n820

8 1527

23 1-111-1

A,

107.&7

Konlenut mhux inqas !I'Iinn 99.5'" AI

Tnb jew fol ji t kejknin lewn il_fidda

PiJIMnt Mo:taI 1. AUl'1.Im _ Au

lnorpniku

231·16S-9

"'hob

197.0

Tnb jew falji t keJlcnin lewn id-deheb

Mhu~ lip! minn 7'11>1

Wan Ii jnhall &hal kollo.t

Mhul iijed minn 4'11>

CI Pil~ Rro". RubinpiJIMnt. CannilX 68

Il·LiIhoI RobilX 8K jikkonsini essenzj.alment rCilcium 1-hydroly-4-(4-

methyl·2 .... lfonalOphenyIWJ)-2·lLIphthalentcarbolyla~ u marer,if, koloranti

suliidjarja llinWen 11\1.' lima, kkwur w-kaltju uljew $Olfllllal-Ultju b/IaIa

I-komponrrxi mhlll ikkuluriti printi~i _

MOfI(W!o

I ~KSO : I

Numru lal-Indici lal -~ulur

2zt.-109-S

C"kiu m 3-hydrol y-4--(4- mel hyl-2-iulfonalophenylazo}-2- n.phlhak~­

Ismijiel kimiCi

Carbol)'la\e

,o,S

C" H "C"'~

Fonnul a kimila

Pii ITIQkkul;u;

Kom~nu( mhUl inq'" minn 9O'il> tal-mak'Tji lroIoranti totali

E 1*

200 f, C1I 442 nm fi dimethylfonnanooe

I, m

Tnb allmar

Idcntifi'uzl:joni

MlWImu fi di .... thylfomwrude Ii CII .w2 nm

O.s*

Mhul it jed minn

Malerji lroIonnli sussidjarji

Komposti Oflaniti minbarra m.~ rj.

kolonnti

2-Am ino-S-meth)"1 bel'u:ene~u I fOAk

Irid, Cllcium ""',

Mhul it jed minn 0.2'Ko

3-h ydrol y -2 -napluhakl>f'C'Wb<ll )'1 '"

IIC'id, elk-ium sal,

Mhul itjoed minn 0.4%

.romatiC; pflmarj; mhn

Ami~s

Mhul ii;ro minn 0 .01% ("~ni bhala anil; .... )

iul fonlt,

"'hnn WIUZljoni la' I'll ',mhU l ii;ro minn O~

Ma!.tfja fflJilJbbli bl~~ ...

Aneniku

Mhul it jed miM 3 mstk'

Comb

Mhul iijed m,M 10 mJl\&

Mnkurju

Mhul ii jed minn I mJlkI

Kadmju

Mhul iijed minn I mJl'kI

Mttal li ,qal (bhal Pb)

Malta Government Gazette — Legal Notice 1997 199 — Regulations, 1997

A deep bl ... colour is produced by Iddinl one drop of sulfurlc add 10 one

drop o f saml'le in 2 - ) drops of c hloroform

Ethyl acetare

Methanol

NOI mo~ than SO mg/kg. Ji ngly 01" in combinalioo

Etbanol

Acetone

Beune

Dkhloromethllllt

NOI moOn: lhan 250 mglkg

NO( more lhan 10 mg/kJ

Not more lhan I mglkg

NO( more lhan I mglk,

NO( more than 40 mg/kJ

Natural Yellow 27

Lycoptne is obtained by soh·tnt txlrnClion o f the n;uunJ SlrtinJ o f red

iOntlllOtS (LJCOIWrsirott tJC"u/ellllUfl 1.) wilh subsequen! ~moval of \til

soI'·enl . Only the following JOlvems may be used: dich1orornetlw>e,carbOlJ

dioxide .ethyilltetate. acelone. propan-2-o1. memaool. emaool , hexane:. "fbe

IlUljof colouring pri ndpk o r lOO1al~J ;slywpene. mioor amoonl s o rOlher

can)t(: noid pigments may be prese'll. Beside !he 01"", colou, pi~nu lhe

prodlK:l may conwn oils . (au , wun. and n.you, componenl$ 1IlI1U.wly

OCX'WTin, in IOmaroes .

15 125

C.,H,.

Conlcnl not leu thin 5'10 IOlaI colourinS IIUIUn-I

E ['10

3 45(l alcI 472nminheune

I,m

DarIr. rN viKOUJ l;quod

Muimum in '-::1_ II. C11 472 nm

Ethyl aoetIle

Methanol

'''''''''

Nor moR Lhan 50 ms'k,. sinSly (II' in combinalion

"""""

"',-

PropfIn·2-ol

Dich~

not moR!hIII 10 mN

Not moR \han 3 mg/k,

Noc moR than 10 mg!k,

;\:OC moR lhan 40 mJlkJ

CI Food Orange 6

These speci fICations apply 10 predominantly all trans isomer of ~8'_

carocena/ IOgeIher with minor &mOUnU of otM carolrnoids. Dil~ and

stabil ized forms are prepared from ~-apo-8' <arolenal meeting these

$pecifw:alions and include JQlutionsor suspensions oflJ-apo-S' ~ in

edible fats or oils, emulsion s Ind water di sperli ble powders. T~se

p1l'parations may have different cisJtrans isomer ralios .

""111

214-171 -6

IJ-Apo-8 ' <arolenal. Tranl-IJ-apo-S' carotene-aldehyde

416,65

NO( less ttwJ 96'll> of total oolouring matten

E I'll>

,= 2 640 1IC1460 _ 462

nm in cyclohe1ane

[)4rl:; viole! CrySl.ll1 with mo:!allic lustre Of' crystalline powder

Maximum in cyclohcxane 8.460 _ 462 nm

Not tnOfl! than 0,1'll>

Caror.enoids other ttwJ IJ-apo-S' <aroIrnal

rIOt more than 3.0% of lOIal 00lourin8 matlen

NO( ~ than 10 mglkg

NO! more than I mglkg

NO! more than I m&lks

Cl Food Ornnge 7, Il-apo-S- -carotero:;>ic c,te,

These specifICations apply to predominantly all trans isomer of ll-apo-8'-

carotenoic acid ethyl es~r together wilh mioor amounts of otl1ercaroteooid'i.

Diluted and stabilized forms are prepared from Il-apo-S" -carate""ic acid

ethyl eSler meeting lhese specificalions and indo"" solutions Of Slispensions

of 1J-ap<;>-8 - -caroteooic acid ethyl ester in edible fals or oils, emulsions and

water dispersible powders . These preparations may have different cis/lmns

iSOrm'r ratios

4OS25

214-173·7

Il-Apo·S" -carotenoic acid ethyl eSler, ethyl S- -apo-IJ-carotene-S' -oate

C" H .. O,

46(],70

Not les s Ihan 96% of total colouring matters

E 1% 2550 at ca 449 nm in cyclo/lexane

km

Red 10 violet_red crystals or crystalline powder

Maximum in cydohexane at ca 449 nm

Not more than 0,1%

Caro~noids other than !l-apo·S" -caro~noic acid ethyl esler: nol more than

3.0-% of lotal colouring mailers

NOl more lhan 3 mgfkg

NOl more than 10 m!lkg

Not more than I mgfkg

Not more than I mgfkg

Not more Ihan 40 mgfl:.g

Mixed Caro1el1Oids, Xanlhophylls

Lulein is obtained by solvent urn.ttion of the natural strains of edible fruits

IlIId plants, grass, lucerne (alfalfa) IlIId W~leJ erecw. The main oolouri"t

prindple consists of caroICnoids of whid! IUlein and ilS fany acid esltn

a«'O\InI for the major pan. Variable UIIO\InIS of C'aroIefIn will also be prHent.

LUlein may contain falS. oi ls and wues naturally occuring in the p llllt

rtl3leriaL

O<tly the fOllowing loOI"enlS may be uS<'d for the ntr&c:tion : methanol. ethanol.

propan·2.o1, hexane . ~tone. methyl ethyl ketone , dichloromethane and

carbon dio ~ ide

Carotenoid

Content o f IOIaJ COIOllring maner not len Lhan 4% calcu lated as lutein

t.

2 S.50 at 44S nm in dllorofonnlethanol (10 • 90) or in

hexaneicthanollacelOne (SO . to + (0)

Dad .yellowish bro,,'n liquid

Mu imum in chk>n::>fonnleihanol (10 + 90) at ca 44S nm

M

._

A_

Methyl ethyl telOne

Not rroore than 50 mgltg. singlyor in oombinatioo

E_

Propart-2.o1

Hexane

DichIOfOmeth~

nor more than 10 rnglkg

NO! more than) rnglkg

Not more than 10 mglkg

Not more lhan I mgfks

Not more IlIan I msJ1cs

CI Food Oran~ 8

These specificalionSl pply 10 predominanily all lrans i$Olllef"S of canllw.anthin

logether with minor amounts of other clU'QlCnoids . Dil uted and 5Labi lilJ.'d

form. are P"'l'<lred from camhllJ.llJIthin meeting these specifICations and

include sol ut ions 0<" WSj)ensions of canthu anthin in edi ble fau: or oi l.,

emulsions and .... aler dispersible powders. These preparations may ha~

di ffn-entcisllnn. isomer ratios .

408>0

p..Carotene-4 ,4 ' -dione, c."t)wanlhin. 4 .4 ' -dioxo-Ikarotene

Noc less tJun 96'lt of \QI.aI co/ouri nll mllllers (expn:Moed 15 canlhu anthin)

,,,

"m 2 11468

200 at ea 485 nm in chloroform

- 472 nm in cyc lol>uane

11464 - 467 nm io petroleum ether

DH-p Vio~1 crystal. or crystalline po .... tkr

Muimum in chloroform al ca 433 nm

MlU imum in cydol>uane al468 - 472 nm

Muimum in ""troleum elher at 464 - 467 nm

Not nlOl"e than 0,1 %

Can>ttno!d5 othoor lhan eamhuanthin: not mon: than 5.0% o f total coiourinll

~."

NOt mort: than J mgi1<g

NOt mort than 10 mglkg

Not more th,in I mgltg

NOt more than I mglt.g

NOt more than 40 mgltg

~tRed

Beet red Ii obtained from the roots of rWLlI1Il $/IlIiniof red beets (&ra ' ''Ig<JrU

L. var. fl'br/J I by pressing crushed bttt as presI juice or by lIQueous u traction

of sb~ beet roOts and subsequent enridlment in the acti"e principle .

n.c colour is oompo$rd of different pigrmnu all belonging 10 the class

betalaine. n.c main colouring principle consists ofbetacyanins (red) ofwhidt

betanin accounts for 7S - 9S'lo . Minor amounts of betaunlhin (yellow) and

degradation products of betaJaj"". (Iigltt brown) "",y be pre~nt .

Besides the colour pigments tlte juice Of extract consists of sugan. ulu,

andlor proteins naturailly occuring in ",d beets. Tlte solution may be

concentrated and SOITl(' products may be ",fined in order to remoVe !!lOSt of

the sugars. ults Bod proIcim.

BetaJai ne

23I.o28-S

r

(S-( R • ,R • ).4-( 2-( 2·C .rbo~ y. S(~· D· g I ucopynnos y Io.l Y 2 3·d iltydJ0.6.

hydrox y·1 H· indo!· I • yl)e then yl)-2.3-diltydro-2.6- pyridi ne-d icarbox ylk acid;

1-(2 -( 2l>-dicarbo~ y. I ,2.3 ,4-ldnllt ydr0-4-pyridy I ide ne)eth y 1 ide ne)· S·p..D-

gJuropyranO$y loxy)-6- ltydroxyindolium-2-carbol ylau

Conlent orred colour (upresKd as beWline) is IlOIless tIw! 0,4'"

1120atcaSJSnminllQ\lf'OUs9)iulionaipHS

E 1%

1=

Red or darIc: red liqui d. paste, powder or wlid

Maximum in water of pH S aI c. SJS nm

B IS8 1

NO! ~ than 2 & nittalC .monl& of red colour (» calculated from ass..y) .

No! more INn ) m&fk.

NO!II'ICft than 10 mJ!ka

m"".

Noc _

than 1

NO! more tIwI 1m"".

NO! more than 40 mg/kg

Anthoc)'alliM _ otuined byeAU'aCtion willl.wlplUlCd "'., ,Kidi rled _ ,

carbon d im.ide , methanol or ethanol from the natural I tl1l;ns o f ~~

and edible fnoiu. Anthtw;yanins oe>ntain rommon oompononu of the oauroe

ma!erial. lIam"'y anthocyanine,or&anic lCidi. Wlni,.,.luprs. minef&ls elC ..

bulllOl ncceHarily in the same poopootions as foond in the souroe maleria! ,

Anthocyanin

W&-4l8 -6 (cyanidi n); WS, l lS-6 (peon idin); W80431'() (dc: lp/linidin)

211-403- 8 (rnalvidin): 2OS- 127-7 (pclargonidin)

3J' /0 ' j,7-~lAhydloAy,n.V)'Ii~m chlori<k (cyMidin)

),4' j,7- TdBhydro~y,3' -methoJ:ynavylium chloride (pconidin)

3,4' j,7·T etrahy~xy- )' ..'i' -dimelhoxyflavylium chloride ( malvidir1)

lj.7- Tnhydr~u y·2-(3,4 j. IrihydroxypbenylH -bcnxopyrylium c hloride

(dc:lphinidin)

3Y 4' j,7 .~ntahydroxy-S' .methoxyflavylium chloride: (I'l'tunidin)

3.S .7 _ T ri hydrox y- 2·( 4 · hyd ro A yphen yl)· I-be nzopy r i I i u m c h lo dde

(l'l'larJOnidin)

CylUlidin

C " H" O,C I

Peonidin

C ".H" O,CI

M.J\idin

C,,H,,O,C I

Delph inidin

C"H"O,C I

~lUnidill

C ".HuO,CI

~IarJooJdin

C"H"O.CI

322,6

Cyllllidin

336,7

Peonldin

"".

3<».7

Malvidin

Delphinidin

3S2,7

I'!tunidin

306.7

I'!I...,onidin

Purp\ish-~d liquid. po .... der or paSie, having a slight characteristic odour

Muimum in me1haool with 0.0 1% cone. HCI

535 nm

Cyanidin

532 nm

Peonidin

542 nm

Ma lvidin

"""m

Delphinidin

543 nm

Petunidi n

530 nm

I'f:largonidin

l Not

Methanol

f

I"I"ICIft than SO m&lkll. singly or in combination

Ethanol

Not more ttlan I 000 m&lkg ~r percent pigment

Not I"I"ICIft than 3 mglkg

Not more ttlan 10 mglkg

Not more than I mglkg

Not more tllan I mglkg

Not more than 40 mgfkg

C] Pigment White III. Cha]1;

Calcium cart>onate i. tho produd obtained from ground limeslont orby the

precipitation of calcium ions with carbonate ions.

Inorganic

17220

Calcium carbonate: 201439-9

Limestone

2 15-279-6

Calcium cart>onate

caCo,

100.1

Content not ICS$ than 98% on the anhydroo~ basi~

White crystalline or amorphous.odourl e~~ and (asteles~ powder

Practically insolubl~ in water and in aloohoL Dissolves with effe~scencc

in diluted acetic acid. in diluted hydrochloric acid and in di luted nitric acid.

and the resulting solutions. after boiling. give positi V<' tellS for calcium.

NO! more than 2P% (200 OC, 4 hou,,")

Not more than 0.2 %

NO! more than 1.5 %

Not more than 50 mglkg

Not mon: than ]00 mg/kg. singly or in combination

Not more than 3 mglkg

Not more than 10 mglkg

Not more than I mglkg

C I Pigment White 6

Titanium Dioxide consists essentially of pure anatase titanium dio~ide whkh

may be coated with small amounl.'i of alumna and/or silica to improve the

technological properties of the product.

loorganic

77891

236-675-5

Titanium dioxide

TiD,

79,88

Cootent not less than 99% 00 an alumina and silica·free basis

AnlOlphoos whire powder

Insoluble in water and organic wlventS , Dissolves slowly in hydronklOlic

Kid Md in hot COI'Ittntr1l!ed 5ulfunc Kid.

NO! more than 0.5% ( I O~ ·C, 3hounJ

t""" I ,()'l. on I VOlatile mailer fret, oois (800 0(;)

NOI _

Total not 100I'I: than 2.0%

than 0.5% 00 an alumina and silica·free oois and, in addition,for

NOI _

producu ronwning alumina and/or silicl, not ~ than I J% on !be ha5is

of the produ" as sold.

Notmorel hanOJ%

Noc ~!""" SO mglkg by IOtaI diswlution

Not more than 3 mglkg by IOtai dissolution

NOI more than 10 rnglkg by lOW di,wlution

Noc more than I mgikl by IOlai dissolution

Not more than SO mglkg by IOIaI di 5iOlution

JronOxide Y~llow : CI Pigmenl Yellow 42 Ind~)

CI Piglllt'ni Red 101 and 102

Iron Oxide Red

Iron Ox ido. Black: CI Pigmenl Black I I

Iron oxid.: and iron hydroxidu Ir. produced symhetically and ron,i,1

.,.en(ially of anh)'droui andlor hydrated iron oxides. TI>e rani. of hlld

i""Jude. y.Uows, rN •. bro'-'ns and blacks. Food quality iron oxides Iff

primarily di~tingui,hed from t«hnK-alllf"'lM by IhC' comparati'it'ly low k:~.b

of rotItamll"l;ltion by oth<>r metals . This is ach~ved by the selection and contrOl

of LI'Ie soon:c of ~ i...., andfor by the e~lCnt of t hrmicr.1 purification during

the manufacturing pl'lJCess.

Inorganic

Iron Oxide Yellow: 77492

Iron O~ide Rw

77491

Iron O~ide Black: 77499

Iron Oxide Yellow: 257-098-5

Iron OAide Red;

215-168-2

Iron O.ide Black: 235-442-5

Iron O~ide Yellow: lIydrated ferric o~ide , hydrated iron (111) o~ide

Iron Oxide Red: anhydrous ferric Olide. anhydrotl. iron (Ill) o~ide

Iron Olide Black: ferroso f~rric oxide, iron (11. Ill) ox ide

Iron O~ide Yellow

F~OH ) ~U,o

Iron O~ide Rw;

Fe,O,

~,Fe .O,

[ron O:tide Black

g8,85;

FeO(OH)

159,70

Fr,O,

23 1j5

FeO.Fe,o,

Yellow not less tIIan 60%, raj and black not lesslhan 68% total iron, expressed

.siron

Powder: yellow, raj, bro"'n or black in hue

Insoluble in WJter and in organic sol vents

Soluble in concentrated minenJ acids

Not more than 1,0'1.

NotlllOl"e !han 5 mglkg

Not more !han SO mglkg

Not more Ihan 5 mglkg

NotlllOl"e than 100 mg/'kg

Not more than SO mglkl

By total di SiOlulion

Not more than 20 mglll

Not more than I mglltg

Not more than 200 mglltg

Not more than 100 mglkg

C I Pigment Metal. AI

Aluminium powder is composed of finely divided panicles o f aluminiulII.

The grinding mayor may noI be c..,;."j out in tIw: prtWACf of aliblc ve~

oils and/or food llidditive quality fany acids . I! is tll.'f from admixwre with

substances other than edible vegcUlblt oils and/or food IIddi tivc quality rally

acids.

77000

231-072-3

Alum inium

AI

NOilen 1han 99% calculated as AI on an oil-f~e basis

It. silvcr)'-FY !",wOn" or liny sheets

JnsoIuble in water and in organic soiv"'t!I . Soluble in dilute hydrochkn

acid_The ~5tllting solution givcs positive tests for aluminium .

Not n'iOfT than 0.5% (IO~"C . to COOSUlnl weight)

NOi more than 3 mgl\::g

Not more than to mgl\::g

NOI II1OIl' than I mgl'kg

1'0t more than 40 mgl\::g

Argentum. AS

lnorsa nic

TIS20

8 1587

23!-131-)

Silvn-

A,

107,87

Content not len than 99.5'1, AI

Silver<Olou~ powdtr« tiny sl'ftu

Pi&meDi Metal l , AUI1Im , Au

Inorganic

"..,

231-1(6..9

"1P

Conlent oot leu than IJO'I, Au

Aller c:omplele dissolution

CI Pigmmt Rtd n , Rubin~QI , Carmillf 6B

Litho! Rubinr BK ~JiJIS essentially o f cllc ium 3-hydroxy-4~4-methyl-2-

su i fooatophenylalo)-2_naphthaJeneclfboxylate and subsidillf)' tolourinl

matters together with Wlter. c:akium chloride andI« c:akium lulfate as the

principAl untoloumi c:omponmu.

Colour l..!os No

..... , ...

C.lci,,,, J-hydro. y .... _( 4- ..... thyl .! . '" I rOl\llophe~ylazo}- 2 -"*PhI ..........

OIomo.lI formula

"'.,

eo....", _ ..... _ 90'lIo I0Il1 coIourinJ mauen

200 .. "" 4-'1 nm in di .... "'ylbmamide

".

E 1'110

Dncriplioll

Muim"", in dimcthylfornumidc tin 442 nm

S.Midixy coIourinl m'"~'''

0rpNc c ......... ocher _

coICMr-

...

in.mau~

1· Amino- "lMIhy 1 bcnu ... ",1 fonic

than 0.2110

KMI .cltJci .... Mil

SOl _

J .hydnl. y. 2 .naphthalrnn:ar'bo. )'Iic

.,,11

IOI;1d. calci.",

SOl m<n ,han 0 ,4\\

U ~ulfon"lr4 pri", .. y 1IO""'ic

~~.

"".'ion of pH 1. _ _ lhan Ol'i'o

F""" "

SOl """" than) .... "' •

.....

SOl mon: than 10 rnaIlI

Not mon: than t milk.

c.dmium

""'00,_. _"... . .. _J,e-,..,.

""'''' 'I "r-.I 0.0 oio_ Ii ~w.mwl," - l.l)ofn~ - _ _ ..

c.......-,........ f'rr ..

n·' .....

p .. "}O ~.c" .... . ,. .. -.} .......

M""",,,

.... " ,--1.20, _ "", v..I,](Jr

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